自由基羰基催化下苯胺与大体积碘化烷基的直接α-交叉偶联

IF 9.2 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY CCS Chemistry Pub Date : 2025-02-04 DOI:10.31635/ccschem.025.202405131

Chengkang Hou, Longjie Huang, Lei Wang, Siqi Liu, Guoqing Zhao, Kuiling Ding & Baoguo Zhao1The Education Ministry Key Lab of Resource Chemistry, Shanghai Frontiers Science Center of Biomimetic Catalysis, College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 2002342The Frontiers Science Center for Transformative Molecules and the School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240

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引用次数: 0

摘要

CCS化学，领先于印刷。α-氨基自由基是一种高活性的有合成价值的物质。然而，它们的不稳定性和寿命短限制了它们在有机合成中的应用。这项工作已经证明了原位生成持久性α-…的催化策略。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Direct α-Cross-Coupling of Benzylamines with Bulky Alkyl Iodides Enabled by Radical Carbonyl Catalysis

CCS Chemistry, Ahead of Print.
α-Amino radicals are highly reactive and synthetically valuable species. However, their instability and short lifetime limit their applications in organic synthesis. This work has demonstrated a catalytic strategy for in situ generation of persistent α-...

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来源期刊

CCS Chemistry Chemistry-General Chemistry

CiteScore

13.60

自引率

13.40%

发文量

475

审稿时长

10 weeks

期刊介绍： CCS Chemistry, the flagship publication of the Chinese Chemical Society, stands as a leading international chemistry journal based in China. With a commitment to global outreach in both contributions and readership, the journal operates on a fully Open Access model, eliminating subscription fees for contributing authors. Issued monthly, all articles are published online promptly upon reaching final publishable form. Additionally, authors have the option to expedite the posting process through Immediate Online Accepted Article posting, making a PDF of their accepted article available online upon journal acceptance.