Nizami Israfilov, Nathalie Kyritsakas, Abdelaziz Jouaiti and Sylvie Ferlay
{"title":"探讨芴基二羧基配体的配位聚合物的形成及其吸附能力","authors":"Nizami Israfilov, Nathalie Kyritsakas, Abdelaziz Jouaiti and Sylvie Ferlay","doi":"10.1039/D4CE01201A","DOIUrl":null,"url":null,"abstract":"<p >Two new coordination polymers (compounds <strong>1</strong> and <strong>2</strong>) based on the use of a V-shaped ligand <strong>L</strong> (9,9-bis(4-carboxyphenyl)fluorene) combined with Cu(NO<small><sub>3</sub></small>)<small><sub>2</sub></small> or Zn(NO<small><sub>3</sub></small>)<small><sub>2</sub></small> were synthesized and structurally characterized by single-crystal X-ray diffraction. These compounds add to the list of very few examples of reported CPs derived from ligands with a fluorene core. X-ray diffraction analysis revealed the structures of the compounds; 2D (<strong>1</strong>) and robust 3D (<strong>2</strong>) structures were reported, and their sorption and emission properties were analysed. Additionally, it was possible to isolate the following compounds as side products: compound <strong>4</strong>, a 2D compound that is isomorphous to <strong>1</strong>, and compound <strong>3</strong>, a polymorph of <strong>1</strong>.</p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 8","pages":" 1206-1213"},"PeriodicalIF":2.6000,"publicationDate":"2025-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/ce/d4ce01201a?page=search","citationCount":"0","resultStr":"{\"title\":\"Exploring the formation of coordination polymers based on dicarboxylic ligands derived from fluorene and their adsorption abilities†\",\"authors\":\"Nizami Israfilov, Nathalie Kyritsakas, Abdelaziz Jouaiti and Sylvie Ferlay\",\"doi\":\"10.1039/D4CE01201A\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Two new coordination polymers (compounds <strong>1</strong> and <strong>2</strong>) based on the use of a V-shaped ligand <strong>L</strong> (9,9-bis(4-carboxyphenyl)fluorene) combined with Cu(NO<small><sub>3</sub></small>)<small><sub>2</sub></small> or Zn(NO<small><sub>3</sub></small>)<small><sub>2</sub></small> were synthesized and structurally characterized by single-crystal X-ray diffraction. These compounds add to the list of very few examples of reported CPs derived from ligands with a fluorene core. X-ray diffraction analysis revealed the structures of the compounds; 2D (<strong>1</strong>) and robust 3D (<strong>2</strong>) structures were reported, and their sorption and emission properties were analysed. Additionally, it was possible to isolate the following compounds as side products: compound <strong>4</strong>, a 2D compound that is isomorphous to <strong>1</strong>, and compound <strong>3</strong>, a polymorph of <strong>1</strong>.</p>\",\"PeriodicalId\":70,\"journal\":{\"name\":\"CrystEngComm\",\"volume\":\" 8\",\"pages\":\" 1206-1213\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2025-01-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.rsc.org/en/content/articlepdf/2025/ce/d4ce01201a?page=search\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"CrystEngComm\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/ce/d4ce01201a\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/ce/d4ce01201a","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Exploring the formation of coordination polymers based on dicarboxylic ligands derived from fluorene and their adsorption abilities†
Two new coordination polymers (compounds 1 and 2) based on the use of a V-shaped ligand L (9,9-bis(4-carboxyphenyl)fluorene) combined with Cu(NO3)2 or Zn(NO3)2 were synthesized and structurally characterized by single-crystal X-ray diffraction. These compounds add to the list of very few examples of reported CPs derived from ligands with a fluorene core. X-ray diffraction analysis revealed the structures of the compounds; 2D (1) and robust 3D (2) structures were reported, and their sorption and emission properties were analysed. Additionally, it was possible to isolate the following compounds as side products: compound 4, a 2D compound that is isomorphous to 1, and compound 3, a polymorph of 1.
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