Hydrothermal processing of primary, waste-activated, and digested sewage sludge: Products characterisation, fate of heavy metals and nutrients, and process integration

Sewage sludges, such as primary sludge (PS), thickened waste-activated sludge (TWAS), and digested sludge (DS), are generated at different stages during the wastewater treatment process. The intrinsic difference in the biochemical and physicochemical properties of these sludge materials may impact their transformation during hydrothermal treatment. This study comprehensively investigated the hydrothermal processing of PS, TWAS, and DS over a range of hydrothermal carbonisation to liquefaction temperatures (180–270 °C). Organic matter conversion increased with temperature but varied with sludge types. The physicochemical, thermal, and textural properties of the produced hydrochar varied substantially with temperature and sludge types. Hydrochar produced from PS at 270 °C had a higher fuel ratio (0.80), calorific value (20.8 MJ/kg), carbon content (48.2 %), and lower ash content (24.4 %) compared to hydrochar produced from other sludge feedstocks. Heavy metals in the feed materials were largely retained in the hydrochar with more than 95 % recovery at all temperatures. Bio-oil products were fractionated into heavy and light bio-oil, and their compositions differed greatly. The aqueous phase product from TWAS and DS had total N, P, K content reaching 5000 mg/L. The findings of this work demonstrate the potential of hydrothermal processing for the valorisation of wastewater sludges into value-added products.