新型高硅黄铜的空化腐蚀:六方晶格结构铜基合金的EBSD研究

IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Wear Pub Date : 2025-07-01 Epub Date: 2025-02-25 DOI:10.1016/j.wear.2025.205983
Jorge Stella , Michael Pohl , Alexander Treff , Björn Reetz
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引用次数: 0

摘要

采用超声空化试验研究了无铅硅黄铜(CuZn10Si5Al1)的空化腐蚀。在相同的测试条件下,与作者先前报道的耐铜基合金相比,新合金具有显着的抗空化性能。与大多数铜基合金相比,测试材料主要由单一的六方紧密堆积相组成,面心立方相的比例可以忽略不计。利用电子后向散射衍射分析了空化引起的塑性变形。这一评价揭示了晶粒取向对局部空化阻力的强烈影响。在孕育阶段,晶粒表面几乎平行于基面表现出明显的孪晶变形,而晶粒表面几乎平行于棱柱面表现出微弱的塑性变形和极低的空化损伤。此外,位于变形差异较大的晶粒之间的晶界被发现最能抵抗开裂或空洞的形成。结果表明,CuZn10Si5Al1合金的高晶体各向异性与单相六方结构有关,从而形成了具有优异抗空化侵蚀性能的组织。
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Cavitation erosion of a novel high silicon brass: An EBSD study of a copper-based alloy with hexagonal lattice structure
Cavitation erosion of a lead-free silicon brass (CuZn10Si5Al1) was studied employing ultrasonic cavitation tests. The new alloy exhibits a remarkable resistance against cavitation in comparison with resistant copper-based alloys previously reported by the authors under identical test conditions. In contrast to most copper-based alloys, the tested material mainly consists of a single hexagonal close-packed phase with a negligible fraction of face-centered cubic phase. Electron backscatter diffraction was employed to examine plastic deformation induced by cavitation. This evaluation revealed a strong influence of the grain orientation on the local cavitation resistance. It is noticeable during the incubation stage that, while grain surfaces oriented nearly parallel to the basal plane exhibit visible deformation resulting from twinning, grains with surfaces oriented nearly parallel to prism planes show weak traces of plastic deformation and very low damage induced by cavitation. Additionally, grain boundaries located between grains subjected to large differences in deformation were found to be mostly resistant to cracking or void formation. It is concluded that high crystal anisotropy related to the single-phase hexagonal structure found in the CuZn10Si5Al1 alloy promotes a microstructure with exceptional resistance to cavitation erosion.
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来源期刊
Wear
Wear 工程技术-材料科学:综合
CiteScore
8.80
自引率
8.00%
发文量
280
审稿时长
47 days
期刊介绍: Wear journal is dedicated to the advancement of basic and applied knowledge concerning the nature of wear of materials. Broadly, topics of interest range from development of fundamental understanding of the mechanisms of wear to innovative solutions to practical engineering problems. Authors of experimental studies are expected to comment on the repeatability of the data, and whenever possible, conduct multiple measurements under similar testing conditions. Further, Wear embraces the highest standards of professional ethics, and the detection of matching content, either in written or graphical form, from other publications by the current authors or by others, may result in rejection.
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