[工作区域空气中硼化合物的测定方法]。

Problemi na khigienata Pub Date : 1994-01-01
V Gŭlŭbova
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引用次数: 0

摘要

用中国绿素法测定工作区域空气中硼化合物浓度的研究证明,在存在天竺葵和铍化合物的情况下是不可行的。根据硼酸与氟离子和铁离子在水杨酸磺酸存在下的相互作用,开发了一种分析硼酸化合物的光谱法,根据硼酸浓度的不同,得到了浅橙色到红色的复合化合物。在波长577 mm处吸收最大。该方法的灵敏度为0.001 mg硼酸在分析样品-2 cm3。在0.001 ~ 0.15 mg硼的显影样品中,硼浓度与光密度呈线性关系。对于浓度为0.001 ~ 0.1 mg的硼,用变异系数%表示的方法的准确度在12.4 ~ 6.3%之间。该方法可以应用的领域是在钛、铜和铅化合物存在的情况下确定的。
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[Methods for determining boron compounds in the air of a work area].

The studies performed with the chinalizarin method the for determination of the concentration of boric compounds in the air of the working area, proved to be impracticable in the presence of geranium and beryllium compounds. A spectrometric method for analysis of boric compounds was developed, based on their interaction with fluoric and ferric ions in the presence of sulfo-salicylic acid, and a complex compound was received of light orange colour to red, depending on the boric concentration. The maximum of absorption was at wave length of 577 mm. The sensitivity of the method was 0.001 mg boric in the analyzed sample -2 cm3. There is a linear dependence between the boric concentration and the optic density of the developed samples of interval 0.001-0.15 mg borium. The accuracy of the method expressed by coefficient of variation in % is in interval 12.4-6.3% for borium concentrations of 0.001-0.1 mg. The field where the method could be applied is defined in the presence of titanium, copper and lead compounds.

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