在最短的B(III)-O键上。

IF 1.9 3区化学 Acta Crystallographica Section B-structural Science Pub Date : 2013-02-01 Epub Date: 2013-01-19 DOI:10.1107/S0108768112051506

Vasyl Sidey

引用次数: 4

摘要

对于氧硼酸盐的晶体结构，~1.2 Å值可视为B(III)-O键长度的下物理极限。发现B(III)-O键长度小于~1.2 Å的氧硼酸盐晶体结构是可疑的或明显错误的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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On the shortest B(III)-O bonds.

For the crystal structures of oxoborates, the value of ~1.2 Å can be regarded as the lower physical limit for B(III)-O bond lengths. The oxoborate crystal structures with B(III)-O bond lengths shorter than ~1.2 Å have been found to be either doubtful or clearly erroneous.

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来源期刊

Acta Crystallographica Section B-structural Science 化学-晶体学

自引率

5.30%

发文量

审稿时长

6-12 weeks

期刊介绍： Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials publishes scientific articles related to the structural science of compounds and materials in the widest sense. Knowledge of the arrangements of atoms, including their temporal variations and dependencies on temperature and pressure, is often the key to understanding physical and chemical phenomena and is crucial for the design of new materials and supramolecular devices. Acta Crystallographica B is the forum for the publication of such contributions. Scientific developments based on experimental studies as well as those based on theoretical approaches, including crystal-structure prediction, structure-property relations and the use of databases of crystal structures, are published.