没有额外尺寸的不相称晶体学。

IF 1.8 4区 材料科学 Acta Crystallographica Section A Pub Date : 2013-07-01 Epub Date: 2013-05-17 DOI:10.1107/S0108767313005990
Philippe Kocian
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引用次数: 1

摘要

证明了欧几里得平移群,当作为李群处理时,不仅在欧几里得空间中产生平移,而且在任何弯曲或非弯曲空间上产生平移。平移不一定是向量(直线);它们可以是与所考虑的空间参数化兼容的任何曲线。特别要注意的是,平移群的李代数的一个且只有一个有限自由模可以产生调制格和非调制格,调制特征仅由产生格的空间的参数化给出。此外,还证明了结构的衍射图样与自由有限模的作用直接相关。在整个结构的傅里叶变换中,无论结构是否调制,单个细胞的电子密度(即结构因子)的傅里叶变换都是具体出现的。因此,存在一种整洁的分离:一方面是几何方面,另一方面是群体的行动,而不需要额外的维度。
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Incommensurate crystallography without additional dimensions.

It is shown that the Euclidean group of translations, when treated as a Lie group, generates translations not only in Euclidean space but on any space, curved or not. Translations are then not necessarily vectors (straight lines); they can be any curve compatible with the parameterization of the considered space. In particular, attention is drawn to the fact that one and only one finite and free module of the Lie algebra of the group of translations can generate both modulated and non-modulated lattices, the modulated character being given only by the parameterization of the space in which the lattice is generated. Moreover, it is shown that the diffraction pattern of a structure is directly linked to the action of that free and finite module. In the Fourier transform of a whole structure, the Fourier transform of the electron density of one unit cell (i.e. the structure factor) appears concretely, whether the structure is modulated or not. Thus, there exists a neat separation: the geometrical aspect on the one hand and the action of the group on the other, without requiring additional dimensions.

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来源期刊
自引率
11.10%
发文量
0
审稿时长
3 months
期刊介绍: Acta Crystallographica Section A: Foundations and Advances publishes articles reporting advances in the theory and practice of all areas of crystallography in the broadest sense. As well as traditional crystallography, this includes nanocrystals, metacrystals, amorphous materials, quasicrystals, synchrotron and XFEL studies, coherent scattering, diffraction imaging, time-resolved studies and the structure of strain and defects in materials. The journal has two parts, a rapid-publication Advances section and the traditional Foundations section. Articles for the Advances section are of particularly high value and impact. They receive expedited treatment and may be highlighted by an accompanying scientific commentary article and a press release. Further details are given in the November 2013 Editorial. The central themes of the journal are, on the one hand, experimental and theoretical studies of the properties and arrangements of atoms, ions and molecules in condensed matter, periodic, quasiperiodic or amorphous, ideal or real, and, on the other, the theoretical and experimental aspects of the various methods to determine these properties and arrangements.
期刊最新文献
A new vision for Acta Crystallographica Section A. Nets with collisions (unstable nets) and crystal chemistry. Homometry in the light of coherent beams. More about residual values. Direct phasing of nanocrystal diffraction.
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