I2-SDS-H2O体系:一种高效的双催化绿色体系,用于亚胺脱保护和从水中吲哚原位制备双(吲哚基)烷烃。

ISRN Organic Chemistry Pub Date : 2012-08-27 eCollection Date: 2012-01-01 DOI:10.5402/2012/635835
Parasa Hazarika, Pallab Pahari, Manash Jyoti Borah, Dilip Konwar
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引用次数: 1

摘要

建立了一种新型的由I2-SDS-H2O组成的催化体系,在介质中存在吲哚的情况下,裂解2,3-二氮杂-1,3-丁二烯、1-氮杂-1,3-丁二烯、肟和吲哚,利用相应的醛产物原位生成双(吲哚基)烷烃。这一锅简单温和的双催化系统在中性条件下在室温下的水中工作。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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I2-SDS-H2O System: A highly Efficient Dual Catalytic Green System for Deprotection of Imines and in Situ Preparation of Bis(indolyl)alkanes from Indoles in Water.

A novel catalytic system consisting of I2-SDS-H2O has been developed which cleaves 2,3-diaza-1,3-butadiene, 1-aza-1,3-butadienes, oximes and in presence of indoles in the medium uses the corresponding aldehyde products to produce bis(indolyl)alkanes in situ. This one pot simple and mild dual catalytic system works in water at room temperature under neutral conditions.

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