一种具有SrSi2拓扑结构的三唑酸酯配体三维手性晶体结构:聚双(μ3-3,5-二乙基-1,2,4-三唑酸-κ(3)N(1):N(2):N(4))硝酸三银。

IF 0.8 4区化学 Acta crystallographica. Section C, Crystal structure communications Pub Date : 2013-12-15 Epub Date: 2013-11-13 DOI:10.1107/S0108270113029788

Feng Jiang, Lin Dai, Yiqiang Shi, Zhixiang Wang

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引用次数: 2

摘要

在标题金属有机骨架(MOF) {[Ag3(C6H10N3)2]NO3}n中，Ag(I)阳离子由来自两种不同的3,5-二乙基-1,2,4-三氮酸盐(detz)配体的两个n原子以线性构型配位。然后，每个Ag(I)阳离子通过μ3-N(1):N(2):N(4)-detrz配体与相邻的两个Ag(I)阳离子连接，得到具有10(3)拓扑结构的三维手性银三氮酸盐结构。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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A three-dimensional chiral crystal structure constructed from a chiral triazolate ligand showing an SrSi2 topology: poly[bis(μ3-3,5-diethyl-1,2,4-triazolato-κ(3)N(1):N(2):N(4))trisilver nitrate].

In the title metal-organic framework (MOF), {[Ag3(C6H10N3)2]NO3}n, the Ag(I) cation is coordinated by two N atoms from two different 3,5-diethyl-1,2,4-triazolate (detz) ligands in a linear configuration. Each Ag(I) cation is then connected to two adjacent Ag(I) cations via a μ3-N(1):N(2):N(4)-detrz ligand, resulting in a three-dimensional chiral silver-triazolate structure showing an SrSi2 (srs) net with 10(3) topology.

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Acta crystallographica. Section C, Crystal structure communications 化学-晶体学

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1 months

期刊介绍： Acta Crystallographica Section C: Structural Chemistry is continuing its transition to a journal that publishes exciting science with structural content, in particular, important results relating to the chemical sciences. Section C is the journal of choice for the rapid publication of articles that highlight interesting research facilitated by the determination, calculation or analysis of structures of any type, other than macromolecular structures. Articles that emphasize the science and the outcomes that were enabled by the study are particularly welcomed. Authors are encouraged to include mainstream science in their papers, thereby producing manuscripts that are substantial scientific well-rounded contributions that appeal to a broad community of readers and increase the profile of the authors.

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