{"title":"富铅羧酸取代钛-铅氧簇。","authors":"Christine Artner, Ulrich Schubert","doi":"10.1007/s00706-017-1972-2","DOIUrl":null,"url":null,"abstract":"<p><strong>Abstract: </strong>The carboxylate-substituted mixed-metal oxo clusters Pb<sub>6</sub>Ti<sub>6</sub>O<sub>9</sub>(acetate)(methacrylate)<sub>17</sub> and Pb<sub>4</sub>Ti<sub>8</sub>O<sub>10</sub>(O<i>i</i>Pr)<sub>18</sub>(acetate)<sub>2</sub> contain a higher number of lead atoms in the cluster core than previously reported compounds. The metal atoms in both clusters are arranged in three layers of different composition, which are connected through oxygen, propionate and/or carboxylate bridges.</p><p><strong>Graphical abstract: </strong></p>","PeriodicalId":18766,"journal":{"name":"Monatshefte Fur Chemie","volume":"148 8","pages":"1371-1377"},"PeriodicalIF":1.7000,"publicationDate":"2017-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/s00706-017-1972-2","citationCount":"5","resultStr":"{\"title\":\"Lead-rich carboxylate-substituted titanium-lead oxo clusters.\",\"authors\":\"Christine Artner, Ulrich Schubert\",\"doi\":\"10.1007/s00706-017-1972-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><strong>Abstract: </strong>The carboxylate-substituted mixed-metal oxo clusters Pb<sub>6</sub>Ti<sub>6</sub>O<sub>9</sub>(acetate)(methacrylate)<sub>17</sub> and Pb<sub>4</sub>Ti<sub>8</sub>O<sub>10</sub>(O<i>i</i>Pr)<sub>18</sub>(acetate)<sub>2</sub> contain a higher number of lead atoms in the cluster core than previously reported compounds. The metal atoms in both clusters are arranged in three layers of different composition, which are connected through oxygen, propionate and/or carboxylate bridges.</p><p><strong>Graphical abstract: </strong></p>\",\"PeriodicalId\":18766,\"journal\":{\"name\":\"Monatshefte Fur Chemie\",\"volume\":\"148 8\",\"pages\":\"1371-1377\"},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2017-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1007/s00706-017-1972-2\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Monatshefte Fur Chemie\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s00706-017-1972-2\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2017/6/20 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Monatshefte Fur Chemie","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s00706-017-1972-2","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2017/6/20 0:00:00","PubModel":"Epub","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Abstract: The carboxylate-substituted mixed-metal oxo clusters Pb6Ti6O9(acetate)(methacrylate)17 and Pb4Ti8O10(OiPr)18(acetate)2 contain a higher number of lead atoms in the cluster core than previously reported compounds. The metal atoms in both clusters are arranged in three layers of different composition, which are connected through oxygen, propionate and/or carboxylate bridges.
期刊介绍：
"Monatshefte für Chemie/Chemical Monthly" was originally conceived as an Austrian journal of chemistry. It has evolved into an international journal covering all branches of chemistry. Featuring the most recent advances in research in analytical chemistry, biochemistry, inorganic, medicinal, organic, physical, structural, and theoretical chemistry, Chemical Monthly publishes refereed original papers and a section entitled "Short Communications". Reviews, symposia in print, and issues devoted to special fields will also be considered.
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