手性磷酸:对映选择性C-H活化的手性前厅

IF 5.4 3区材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2023-01-01 DOI:10.1039/d3cc02293e

Sumit , Devesh Chandra , Upendra Sharma

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引用次数: 0

摘要

对映选择性C-H活化是一种很有前途的获得高对映体过量的对映纯分子的方法，具有良好的区域和化学选择性控制。手性磷酸已发展成为对映选择性C-H活化的先导配体。手性磷酸可以以不同的方式与底物相互作用，从而诱导手性进入体系。本文综述了手性磷酸在对映选择性碳氢化合物活化方面的应用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Chiral phosphoric acids: a chiral lobby for enantioselective C–H activation

Enantioselective C–H activation is one of the promising methods to obtain enantiopure molecules in high enantiomeric excess with excellent control of regio and chemo-selectivity. The chiral phosphoric acids have evolved as the leading ligands in the enantioselective C–H activation. Chiral phosphoric acids can interact in different ways with the substrate to induce chirality into the system. This review summarizes the use of chiral phosphoric acids in the exciting field of enantioselective C–H activation.

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来源期刊

ACS Applied Energy Materials Materials Science-Materials Chemistry

CiteScore

10.30

自引率

6.20%

发文量

1368

期刊介绍： ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.