变压器安装区周围石油烃污染土壤中潜在有毒金属的分析与危害评价。

IF 2.4 Q1 Medicine Journal of Health and Pollution Pub Date : 2019-12-06 eCollection Date: 2019-12-01 DOI:10.5696/2156-9614-9.24.191213
Godswill E Akhigbe, Festus M Adebiyi, Nkem Torimiro
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引用次数: 7

摘要

背景:在发电过程中使用和处理石化产品和其他石油产品造成的土壤污染,由于其对生态系统的不利影响,日益成为全球关注的问题。目的:对尼日利亚Ile-Ife地区变压器安装区周围油污染土壤中潜在有毒金属的浓度和形态进行测定,并利用危害商和危害指数分析确定土壤污染程度。方法:选取变压器油污染区和未污染区(对照)土壤,分别在0 ~ 15 cm和15 ~ 30 cm深度采集土壤,采用原子吸收光谱法测定土壤重金属浓度。对重金属进行分选和危害评价,确定污染土壤的污染程度。结果:两组油浸土壤中镉(Cd)、铬(Cr)、铜(Cu)、铁(Fe)、锰(Mn)、镍(Ni)、铅(Pb)和锌(Zn)的浓度均高于对照土壤。金属也具有相对中等的生物利用度和迁移潜力,残留部分保留了更多的比例。金属的慢性日摄入量(CDI)的增加顺序为:Cd < Cr < Pb < Ni < Mn < Cu < Zn < Fe,而慢性日摄入量风险暴露途径的增加顺序为:cdi吸入< cdi皮肤< cdi摄取。结论:研究得出的结论是,这些金属的浓度在允许范围内,但长期每日剂量很大,可能对长期接触这些重金属污染物的人造成健康危害。利益竞争:作者声明没有经济利益竞争。
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Analysis and Hazard Assessment of Potentially Toxic Metals in Petroleum Hydrocarbon-Contaminated Soils Around Transformer Installation Areas.

Background: Soil contamination resulting from the use and handling of petrochemicals and other petroleum products during power generation activities is an increasing global concern due to its adverse impact on the ecosystem.

Objectives: The present study was carried out to determine the concentrations and speciation of potentially toxic metals in oil-contaminated soils around transformer installation areas in Ile-Ife, Nigeria, and to confirm soil pollution levels with hazard quotient and hazard index analysis.

Methods: Soils from the transformer oil-contaminated and uncontaminated (control) areas were collected at 0-15 cm and 15-30 cm depths and analyzed for heavy metal concentrations using atomic absorption spectrometry. The metals were fractionated and their hazard evaluated to confirm the pollution level of the contaminated soils.

Results: The concentrations of cadmium (Cd), chromium (Cr), copper (Cu), iron (Fe), manganese (Mn), nickel (Ni), lead (Pb) and zinc (Zn) in the two sets of oil-impacted soils were higher than in the control soils. The metals also had relatively moderate bioavailability and mobility potential with more of the proportion retained in the residual fraction. Chronic daily intake (CDI) of the metals increased in the order of: Cd < Cr < Pb < Ni < Mn < Cu < Zn < Fe, while chronic daily intake risk exposure pathway followed the order of: CDIinhalation < CDIdermal < CDIingestion.

Conclusions: The study concluded that the concentrations of the metals were within permissible limits, but the chronic daily dosage was significant and may pose a health hazard to humans with long term exposure to these heavy metal contaminants.

Competing interests: The authors declare no competing financial interests.

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来源期刊
Journal of Health and Pollution
Journal of Health and Pollution Medicine-Public Health, Environmental and Occupational Health
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期刊介绍: The Journal of Health and Pollution (JH&P) was initiated with funding from the European Union and World Bank and continues to be a Platinum Open Access Journal. There are no publication or viewing charges. That is, there are no charges to readers or authors. Upon peer-review and acceptance, all articles are made available online. The high-ranking editorial board is comprised of active members who participate in JH&P submissions and editorial policies. The Journal of Health and Pollution welcomes manuscripts based on original research as well as findings from re-interpretation and examination of existing data. JH&P focuses on point source pollution, related health impacts, environmental control and remediation technology. JH&P also has an interest in ambient and indoor pollution. Pollutants of particular interest include heavy metals, pesticides, radionuclides, dioxins, polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), volatile organic compounds (VOCs), air particulates (PM10 and PM2.5), and other severe and persistent toxins. JH&P emphasizes work relating directly to low and middle-income countries, however relevant work relating to high-income countries will be considered on a case-by-case basis.
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