2-叠氮-N-(4-甲基苯基)乙酰胺。

IUCrData Pub Date : 2022-07-29 eCollection Date: 2022-07-01 DOI:10.1107/S2414314622006216
Mohcine Missioui, Walid Guerrab, Abdulsalam Alsubari, Joel T Mague, Youssef Ramli
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引用次数: 0

摘要

标题化合物 C9H10N4O 的不对称单元由三个独立的分子单元组成,其中两对分子单元在叠氮基团的旋转方向上存在显著差异,而一对分子单元则具有非常相似的构象;N-N-C-C 扭转角分别为 -173.9 (2)、-102.7 (2) 和 -173.6 (2)°。在晶体中,每个独立的分子单元与其滑行面相关的对应物形成 N-H⋯O 氢键,形成沿 c 轴方向延伸的人字形链。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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2-Azido-N-(4-methyl-phen-yl)acetamide.

The asymmetric unit of the title compound, C9H10N4O, comprises three independent mol-ecules, two pairs of which differ significantly in the rotational orientation of the azido group and one pair having very similar conformations; the N-N-C-C torsion angles are -173.9 (2), -102.7 (2) and -173.6 (2)°. In the crystal, each independent mol-ecule forms N-H⋯O hydrogen bonds with its glide-plane-related counterparts, forming zigzag chains extending along the c-axis direction.

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