Sergio Antonio Romero, Daniel Rodrigues Jr, Tarsis Germano, Renato Cohen, Jose´Adilson de Castro, Marcos Flavio de Campos
{"title":"纳米晶Sm–Co–Cu薄膜的矫顽机制：弹簧效应","authors":"Sergio Antonio Romero, Daniel Rodrigues Jr, Tarsis Germano, Renato Cohen, Jose´Adilson de Castro, Marcos Flavio de Campos","doi":"10.1007/s13204-023-02931-1","DOIUrl":null,"url":null,"abstract":"<div><p>In magnetron sputtering, with the simultaneous deposition of SmCo and copper, it is possible for tailoring the coercive field of SmCoCu thin films. Microstructural analysis pointed out that nanocrystalline 2:17 rhombohedral phase with diameter 10–100 nm was obtained, and coercivities in the range between 3 and 8.5 kOe. These characteristics are suitable for magnetic recording. The coercivity mechanisms are discussed. The initial magnetization curve, measured in thermally demagnetized samples, is used to discuss the coercivity mechanisms. A spring effect in the samples is observed. The spring effect is due to reversible rotation of magnetization and indicates that the coercivity mechanism is nucleation or coherent rotation of single domain size nanoscale grains. Structural data refined with X-ray diffraction Rietveld analysis for Sm<sub>2</sub>(Co,Cu)<sub>17</sub> rhombohedral phase, Sm(Co,Cu)<sub>5</sub> phase and cubic oxide Sm<sub>2</sub>O<sub>3</sub> phase are provided.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"13 9","pages":"6353 - 6372"},"PeriodicalIF":3.6740,"publicationDate":"2023-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13204-023-02931-1.pdf","citationCount":"1","resultStr":"{\"title\":\"Coercivity mechanisms in nanocrystalline Sm–Co–Cu thin films: the spring effect\",\"authors\":\"Sergio Antonio Romero, Daniel Rodrigues Jr, Tarsis Germano, Renato Cohen, Jose´Adilson de Castro, Marcos Flavio de Campos\",\"doi\":\"10.1007/s13204-023-02931-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In magnetron sputtering, with the simultaneous deposition of SmCo and copper, it is possible for tailoring the coercive field of SmCoCu thin films. Microstructural analysis pointed out that nanocrystalline 2:17 rhombohedral phase with diameter 10–100 nm was obtained, and coercivities in the range between 3 and 8.5 kOe. These characteristics are suitable for magnetic recording. The coercivity mechanisms are discussed. The initial magnetization curve, measured in thermally demagnetized samples, is used to discuss the coercivity mechanisms. A spring effect in the samples is observed. The spring effect is due to reversible rotation of magnetization and indicates that the coercivity mechanism is nucleation or coherent rotation of single domain size nanoscale grains. Structural data refined with X-ray diffraction Rietveld analysis for Sm<sub>2</sub>(Co,Cu)<sub>17</sub> rhombohedral phase, Sm(Co,Cu)<sub>5</sub> phase and cubic oxide Sm<sub>2</sub>O<sub>3</sub> phase are provided.</p></div>\",\"PeriodicalId\":471,\"journal\":{\"name\":\"Applied Nanoscience\",\"volume\":\"13 9\",\"pages\":\"6353 - 6372\"},\"PeriodicalIF\":3.6740,\"publicationDate\":\"2023-07-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1007/s13204-023-02931-1.pdf\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Nanoscience\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s13204-023-02931-1\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Nanoscience","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s13204-023-02931-1","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Engineering","Score":null,"Total":0}
Coercivity mechanisms in nanocrystalline Sm–Co–Cu thin films: the spring effect
In magnetron sputtering, with the simultaneous deposition of SmCo and copper, it is possible for tailoring the coercive field of SmCoCu thin films. Microstructural analysis pointed out that nanocrystalline 2:17 rhombohedral phase with diameter 10–100 nm was obtained, and coercivities in the range between 3 and 8.5 kOe. These characteristics are suitable for magnetic recording. The coercivity mechanisms are discussed. The initial magnetization curve, measured in thermally demagnetized samples, is used to discuss the coercivity mechanisms. A spring effect in the samples is observed. The spring effect is due to reversible rotation of magnetization and indicates that the coercivity mechanism is nucleation or coherent rotation of single domain size nanoscale grains. Structural data refined with X-ray diffraction Rietveld analysis for Sm2(Co,Cu)17 rhombohedral phase, Sm(Co,Cu)5 phase and cubic oxide Sm2O3 phase are provided.
期刊介绍：
Applied Nanoscience is a hybrid journal that publishes original articles about state of the art nanoscience and the application of emerging nanotechnologies to areas fundamental to building technologically advanced and sustainable civilization, including areas as diverse as water science, advanced materials, energy, electronics, environmental science and medicine. The journal accepts original and review articles as well as book reviews for publication. All the manuscripts are single-blind peer-reviewed for scientific quality and acceptance.
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