苯甲酸酯插层水滑石对丙烯酸涂料UV稳定性的影响

IF 0.8 Q4 ELECTROCHEMISTRY Corrosion Science and Technology-Korea Pub Date : 2020-02-29 DOI:10.14773/CST.2020.19.1.16
T. Nguyen, A. S. Nguyen, T. Thai, G. V. Pham, Thi Xuan Hang To, M. Olivier
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引用次数: 0

摘要

苯甲酸盐是通过共沉淀法嵌入水滑石(HTC-Bz)的。在这种情况下,使用旋转镀膜法在碳钢上沉积了含有0.5 wt% HTC-Bz的丙烯酸涂层。然后,利用场发射扫描电镜(FESEM)、x射线衍射(XRD)和傅里叶变换红外光谱(FT-IR)对HTC-Bz的结构进行表征。实际上,采用紫外分光光度法(UV- vis)测定了HTC-Bz中苯甲酯的含量,并测定了HTC-Bz的紫外吸收能力。采用电化学技术、水接触角测量、热重分析等方法,比较了含HTC-Bz丙烯酸涂层在QUV测试前后的防护性能、疏水性和热稳定性。结果表明:成功合成了具有片状结构的HTC-Bz;在水滑石夹层中插入浓度为28 wt%的苯甲酸酯。此外,HTC-Bz在225nm处有一个紫外吸收峰。综上所述,HTC-Bz的加入增强了丙烯酸涂料的UV稳定性、疏水性和热稳定性。
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The Influence of Hydrotalcite Intercalated with Benzoate on UV Stability of Acrylic Coating
It is important to realize that benzoate was intercalated into hydrotalcite (HTC-Bz) by the co-precipitation method. In this case, acrylic coating with 0.5 wt% HTC-Bz was deposited on carbon steel using the spin coating method. Next, the HTC-Bz structure was characterized by Field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR). In fact, an ultraviolet vision spectroscopy (UV-Vis) was used to determine the benzoate content in HTC-Bz, and the UV absorption ability of HTC-Bz. Using electrochemical techniques, water contact angle measurement, and thermal-gravimetric analysis, we compared the protective properties before and after QUV test, hydrophobicity and the thermal stability of acrylic coating containing HTC-Bz. The obtained results showed that HTC-Bz with a plate-like structure was successfully synthesized; benzoate was intercalated into the interlayer of hydrotalcite with a concentration of 28 wt%. Additionally, it was noted that HTC-Bz has an UV absorption peak at 225 nm. In conclusion, the addition of HTC-Bz enhanced the UV stability, hydrophobicity and the thermal stability of acrylic coating.
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CiteScore
1.30
自引率
66.70%
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