TiO2/RHAC催化声裂解和光解降解苯酚及紫外-可见光谱和高效液相色谱分析

Safni Safni, Eno Okta Patricia, Trisna Ollinovela, Yulizar Yusuf
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引用次数: 0

摘要

本研究的重点是利用光解和声分解方法降解水溶液中的苯酚。研究了催化剂质量、光类型(UV-A、UV-C和可见光)、催化剂类型(RHAC、TiO2和TiO2/RHAC)和处理时间对苯酚降解的影响。苯酚溶液在降解前后用紫外-可见分光光度计和高效液相色谱法进行分析。本研究旨在了解影响苯酚降解的因素,为进一步研究提高苯酚去除效率提供依据。结果表明,使用TiO2/RHAC作为催化剂可以显著提高苯酚的降解率。用催化剂进行超声裂解可实现20.82%的降解,用催化剂降解可提高到50.57%。光解降解率达到29.06%,使用催化剂后降解率提高到91.99%。在催化剂质量为30mg TiO2/RHAC催化剂的情况下,使用UV-A光5小时可实现最高降解百分比。HPLC分析证实苯酚浓度降低并且存在中间体化合物。TiO2/RHAC催化剂显示了在水溶液中有效降解苯酚的潜力。
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Degradation of Phenol Using Sonolysis and Photolysis by TiO2/RHAC Catalyst and Analysis with Spectrophotometer UV-VIS and HPLC
This study focuses on the degradation of phenol in aqueous solutions using photolysis and sonolysis methods. It investigates the impact of catalyst mass, types of light (UV-A, UV-C, and visible light), types of catalyst (RHAC, TiO2, and TiO2/RHAC), and processing time on phenol degradation. The phenol solutions are analyzed before and after degradation using Spectrophotometer UV-Vis and HPLC. The research aims to understand the factors influencing phenol degradation and provide a basis for further studies to enhance the efficiency of phenol removal. Results show significant improvements in degradation percentages of phenol by using TiO2/RHAC as the catalyst. Sonolysis achieves a degradation of 20.82% with a catalyst, which increases to 50.57% with the catalyst. Photolysis achieves a degradation of 29.06%, which rises to 91.99% with the catalyst. The highest degradation percentage is achieved using UV-A light for 5 hours with a catalyst mass of 30 mg of TiO2/RHAC catalyst. HPLC analysis confirms a decreased phenol concentration and the presence of intermediate compounds. The TiO2/RHAC catalyst demonstrates the promising potential for efficient phenol degradation in aqueous solutions.
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