智能手机光谱技术在教育动力学研究中的应用分析验证

IF 1.5 4区 化学 Q3 CHEMISTRY, ANALYTICAL International Journal of Analytical Chemistry Pub Date : 2023-04-20 DOI:10.1155/2023/3729633
S. Raissi, F. Fakhfakh
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引用次数: 0

摘要

自去年以来,基于智能手机的光谱学的使用一直在持续增长。它的优点是每个人都可以广泛使用。最重要的是,它仍然是一种适应教育环境的低成本方法。但是,和所有的分析方法一样,需要对其进行验证,以确保其结果的可靠性。在这项研究中,我们提出了验证过程的步骤,其统计测试应用于二碘的剂量。夏皮罗-威尔克试验表明,我们的方法具有随机性。采用科克伦检验进行方差齐性分析,证实了该方法的准确性。Fisher检验表明,I2浓度与响应之间的相关模型呈线性关系。响应与浓度的关系为A = 1000 C + 0.002。根据模型的线性回归参数,推导出定量限,XLq = 4·10−5 mol·L−1,XLd = 1·10−5 mol·L−1。由于样品的紧密性,I2用量法成功地应用于碘定量,在动力学研究的背景下,以最小的系统故障监测丙酮的碘化。该方法成本低,便于在教育实验室中使用物理方法。
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Analytical Validation of Smartphone Spectroscopic Technic Used in an Educational Kinetic Study
Use of smartphone-based spectroscopy is showing a constant growth since last year. It presents the advantage of being widely available for everyone. The most important thing is that it is still a low-cost method adapted to the education context. However, as all analytical methods, it should be validated to ensure the reliability of its results. In this study, we present the steps of the validation process with its statistical tests applied to the dosage of di-iode. Shapiro–Wilk test revealed that our method has a random character. Homogeneity of variance analyses using the Cochran test confirmed the precision of the method. The Fisher test revealed the linearity of the model of correlation between I2 concentration and the response. The relation between response and concentration is A = 1000 C + 0.002. From the parameters of the linear regression of the model, we deduced the limits of quantification and XLq = 4·10−5 mol·L−1 and XLd = 1·10−5 mol·L−1. Thanks to tightness of the sample, the method of I2 dosage was successfully applied in iodine quantification to monitor acetone iodination during time in the context of kinetic studies with minimum system trouble. Being low cost, this method can facilitate access to physical methods in educational laboratories.
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来源期刊
CiteScore
3.10
自引率
5.60%
发文量
117
期刊介绍: International Journal of Analytical Chemistry publishes original research articles that report new experimental results and methods, especially in relation to important analytes, difficult matrices, and topical samples. Investigations may be fundamental, or else related to specific applications; examples being biological, environmental and food testing, and analysis in chemical synthesis and materials processing. As well as original research, the International Journal of Analytical Chemistry also publishes focused review articles that examine the state of the art, identify emerging trends, and suggest future directions for developing fields.
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