450 nm和808 nm连续激光点火低变质煤

IF 0.5 Q4 CHEMISTRY, MULTIDISCIPLINARY Eurasian Chemico-Technological Journal Pub Date : 2022-07-25 DOI:10.18321/ectj1321
B. Aduev, G. Belokurov, I. Liskov, D. Nurmukhametov, Z. Ismagilov
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引用次数: 1

摘要

本文对比研究了低变质煤系(褐煤和高挥发性C烟煤)在波长为λ = 450 nm和λ = 808 nm、照射时间为1秒的激光照射下微粒点火的动力学和能量特性。没有过渡到静止燃烧。点火延迟时间随辐射功率密度的增加而单调减小。结果表明,采用波长为λ = 450 nm的激光辐射可以降低煤系的点火能量成本。对煤点火能量特性的测量结果表明,煤对辐射的吸收具有量子性质。在着火初始阶段测量的煤颗粒发射光谱有两个组成部分:CO (CO2*)火焰和两种煤阶与发射的碳颗粒加热到T>2000 K相关的热辉光。在随后的阶段,在光谱中只观察到热谱在T~2000 K的加热碳颗粒的发光。
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Ignition of Low-Metamorphized Coal with Continuous Lasers at Wavelengths 450 nm and 808 nm
The paper presents the results of a comparative investigation into the kinetic and energy characteristics of the ignition of microparticles of low-metamorphized coal ranks (lignite coal and high volatile C bituminous coal) under the impact of laser radiation at the wavelengths λ = 450 nm and λ = 808 nm with an exposure time of 1 sec. Coal ignition is carried out only during irradiation. There is no transition to stationary combustion. The ignition delay time decreases monotonically with increasing radiation power density. It is established that the energy costs of ignition of the studied coal ranks may be made more economical by using laser radiation with a wavelength of λ = 450 nm. It is concluded from the results of measuring the energy characteristics of coal ignition that the absorption of radiation has a quantum nature. Two components contribute to the coal particles emission spectra measured at the initial stage of ignition: CO (CO2*) flame and thermal glow associated with emitted carbon particles heated to T>2000 K for both coal ranks. At subsequent stages, only the glow of heated carbon particles with the thermal spectrum at T~2000 K is observed in the spectra.
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来源期刊
Eurasian Chemico-Technological Journal
Eurasian Chemico-Technological Journal CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
1.10
自引率
20.00%
发文量
6
审稿时长
20 weeks
期刊介绍: The journal is designed for publication of experimental and theoretical investigation results in the field of chemistry and chemical technology. Among priority fields that emphasized by chemical science are as follows: advanced materials and chemical technologies, current issues of organic synthesis and chemistry of natural compounds, physical chemistry, chemical physics, electro-photo-radiative-plasma chemistry, colloids, nanotechnologies, catalysis and surface-active materials, polymers, biochemistry.
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