丝胶生态生物材料在涤纶拉伸变形丝生产中的应用

IF 1.5 Q2 MATERIALS SCIENCE, TEXTILES Research journal of textile and apparel Pub Date : 2023-01-19 DOI:10.1108/rjta-07-2022-0086
Abolfazl Zare
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引用次数: 1

摘要

目的从家蚕蚕茧中提取丝胶,并将丝胶粉应用于拉伸变形的聚对苯二甲酸乙二醇酯(PET)纱线上进行纺丝整理。通过傅立叶变换红外光谱-衰减全反射光谱(FTIR-ATR)和亚甲蓝作为活性染料染色,分析了PET纱线表面的反应性。此外,还研究了丝胶、柠檬酸(CA)(作为交联剂)和次磷酸钠(作为催化剂)浓度对假捻变形PET纱线某些性能的影响。设计/方法/方法使用假捻变形机(Scragg-Shirley minibulk,England),拉伸比为1.05,加热温度为120°C,变形速度为100 m min−1,施加3000 TPM的扭转。采用生丝在蒸馏水中以L∶R∶40∶1煮沸120分钟的方法,对丝胶进行了水提取 用滤纸过滤水溶液以去除杂质和不溶性丝素蛋白。最后,将丝胶溶液冷冻干燥,得到丝胶粉。采用“垫干固化”法将丝胶溶液应用于拉伸变形PET纱线上。FTIR-ATR证实了丝胶在PET纱线上的固定。结果表明,拉伸强度、线密度、卷曲收缩和卷曲模量、断裂伸长率和收缩率没有显著变化。相反,在回潮率、垂直芯吸、染料吸收和紫外线防护方面观察到显著增加。在丝胶存在的情况下,电阻率也有所降低。独创性/价值尽管丝胶具有许多有益的特性,但其在纺织工业中作为纺丝整理剂的应用尚未报道。
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Sericin eco-friendly biomaterial as a spin finish in drawn textured PET yarn production
Purpose This paper aims to extracted sericin from the cocoons of Bombyx mori silkworms, and sericin powder was applied onto drawn textured polyethylene terephthalate (PET) yarns as a spin finish. The reactivity on the surface of PET yarns was analyzed through Fourier transform infrared spectrophotometry–attenuated total reflectance (FTIR-ATR) and dyeing with methylene blue as a reactive dye. Also, investigations were conducted on the effects of sericin, citrc acid (CA) (as a crosslinking agent), and sodium hypophosphite (as a catalyst) concentrations on some properties of false-twist textured PET yarns. Design/methodology/approach A false-twist texturing machine (Scragg-Shirley minibulk, England) was used with the draw ratio of 1.05, heating temperature of 120°C, texturing speed of 100 m min−1 and applied twist of 3,000 TPM. The aqueous extraction of sericin was carried out by the boiling of the raw silk in distilled water with L:R: 40:1 for 120 min. The aqueous solution was filtered with a filter paper to remove the impurities and insoluble fibroin. Finally, the sericin solution was freeze-dried to obtain the sericin powder. The sericin solution was applied on the drawn textured PET yarns using the “pad-dry-cure” method. Findings Sericin fixation onto the PET yarns was confirmed by FTIR-ATR. The results showed that there were no significant changes in the tensile strength, linear density, crimp contraction and crimp modulus, elongation at break and shrinkage. In contrast, a substantial increase was observed in moisture regain, vertical wicking, dye uptake and ultraviolet protection. There was also a reduction just in the electrical resistivity, in the presence of sericin. Originality/value Although sericin has been known to have numerous beneficial properties, its application in textile industry as a spin finish has not been reported yet.
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来源期刊
Research journal of textile and apparel
Research journal of textile and apparel MATERIALS SCIENCE, TEXTILES-
CiteScore
2.90
自引率
13.30%
发文量
46
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