固态法合成掺杂钒(V)的二氧化钛(TiO2)及其表征

K. Mustofa, N. Aini, S. N. Khalifah
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引用次数: 2

摘要

TiO2的锐钛矿活性应从紫外提高到可见光的光催化活性,以提高锐钛矿的活性。优化TiO2锐钛矿活性的一个努力是通过使用掺杂剂钒(V)进行掺杂。本研究中使用的合成方法是一种固体反应方法。在这种方法中所采取的步骤包括在高温下研磨和加热。研究中使用的钒(V)的掺杂剂浓度分别为0.3%、0.5%和0.7%。所使用的表征是X射线衍射和UV-Vis漫反射光谱。结果表明,多巴钒(V)的加入使TiO2锐钛矿的粒度、带隙能量和吸收波长发生了变化。而TiO2的结构不变。未掺杂的V-TiO2的晶体尺寸分别为53.21nm、47.67nm、79.65nm和68.99nm。未掺杂的每种TiO2的带隙能量分别为3.309eV、3.279eV、3.2 70eV和3.259eV,而未掺杂的V-TiO2的波长吸收分别为374.9nm、378.4nm、379.5nm和380.8nm。关键词:合成;二氧化钛;钒(V);固态法
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Synthesis and Characterization Titanium Dioxide (TiO2) Doped Vanadium(V) Using Solid State Method
TiO 2 Anatase activities should be increased from the UV to the visible light photocatalytic activity of TiO 2 to increase anatas. One efforts to optimize TiO 2 anatase activity is doping by using dopant vanadium(V). Synthesis method which is used in this research is a solid reaction method. The steps being taken in this methods include grinding and heating at high temperatures. Dopant concentrations of vanadium(V) which are used in the research was 0.3%, 0.5% and 0.7%. and the characterization used is X-ray diffraction and UV-Vis Diffuse Reflectance Spectroscopy. The result shows that there are a changing of particle size, band gap energy, and absorption of TiO 2 anatas wavelength because of dopan vanadium(V) addition. While TiO 2 ’s structure does not change. The crystal sizes of each TiO 2 without doping, V-TiO 2 0,3%, 0,5% and 0,7% are 53.21 nm, 47.67 nm, 79.65 nm dan 68.99 nm.  Band gap energy of each TiO 2 without doping, V-TiO 2 0,3%, 0,5% dan 0,7% are 3.309 eV, 3.279 eV, 3.270 eV and 3.259 eV. While wavelength absorption of each TiO 2 without doping, V-TiO 2 0,3%, 0,5% and 0,7% are 374.9 nm, 378.4 nm, 379.5 nm and 380.8 nm. Keywords : Synthesis, titanium dioxide, vanadium(V), solid state method
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