Kaoru Shomura, R. Mitsuhashi, M. Mikuriya, Y. Kataoka, M. Handa, H. Sakiyama
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引用次数: 0
摘要
x射线方法。化合物在三角形空间群R 3和Z = 3中结晶，晶胞参数a = 11.598(8)Å， c = 25.367(18)Å， V = 2955(4)Å 3。1630个独立反射的R 1 [I > 2 σ (I)]和wR 2(所有数据)值分别为0.0509和0.1565。发现配合物阳离子的对称性属于s6点群，具有与o6给体集的三角压缩八面体配位几何。
Crystal Structure of a Mononuclear Iron(III) Complex, Hexakis(dimethylsulfoxide-κO)iron(III) Tris(hexafluoridophosphate)
X-ray method. The compound crystallized in the trigonal space group R 3 and Z = 3 with cell parameters a = 11.598(8)Å, c = 25.367(18)Å, V = 2955(4)Å 3 . The R 1 [ I > 2 σ ( I )] and wR 2 (all data) values were 0.0509 and 0.1565, respectively, for all 1630 independent reflections. The symmetry of the complex cation was found to belong to the S 6 point group, possessing a trigonally compressed octahedral coordination geometry with an O 6 donor set.
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