“Pondoh Super”蛇果仁中羧甲基纤维素(CMC)的合成与表征

S. Anggrahini, D. Marsono, A. Setiyoko, A. Wahyuningtyas
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引用次数: 5

摘要

蛇果仁纤维素含量高,因此有潜力成为羧甲基纤维素(CMC)生产的替代来源。但要提高CMC的合成效率,还需要优化NaOH溶液的浓度、NaMCA的加入量和基于取代度的反应温度。本研究的目的是确定以超级沙叻蓬都仁为原料合成CMC的最佳工艺条件。影响合成的因素主要有NaOH溶液浓度、NaMCA加入量和基于取代度(DS)的反应温度。采用完全随机设计优化CMC的合成。然后用含水量、粘度、纯度、持水量(WHC)、持油量(OHC)、亮度、结晶度和FT-IR光谱等参数对结果进行表征。优化条件为NaOH浓度为15%,NaMCA浓度为5 g / 5 g,反应温度为55℃。优化后的CMC性能为:DS 0.825,纯度90.86%,含水量7.16 (% wb),粘度3.86 cps,收率142.72 (% db), WHC 2.37 (g/g), OHC 2.31 (g/g),亮度78.48,结晶度32.69%。蛇果仁CMC的FT-IR光谱与CMC标准相似。
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Carboxymethyl Celulose (CMC) from Snake Fruit (Salaca edulis Reinw) Kernel of “Pondoh Super”: Synthesis and Characterization
Snake fruits kernel has high cellulose content thus potential to be an alternative source of carboxylmethylcellulose (CMC) production. However there are several condition that have to be optimized to increase the CMC synthesis which are concentration of  NaOH solution, NaMCA addition, and the reaction temperature based on  the degree of substitution (DS). The aim of this study was to determine the optimum conditions of synthesis CMC from “Salak Pondoh Super” kernel. Some factors that likely influence the synthesis were concentration of  NaOH solution , NaMCA addition, and the reaction temperature based on  the degree of substitution (DS) as the responses. Synthesis of CMC was optimized using completely randomized design. The result then was characterized by several parameters including water content, viscosity, purity, Water Holding Capacity (WHC), Oil Holding Capacity (OHC), lightness, crystallinity, and FT-IR spectra. Optimization was achieved by the use of  15% NaOH solution, 5 gram NaMCA per 5 gram cellulose and reaction temperature of 55oC. The characteristics of the optimized CMC were DS 0.825, purity 90.86%, water content of 7.16 (% wb), viscosity 3.86 cps, 142.72 yield (% db), WHC 2.37 (g/g), OHC 2.31 (g/g), lightness 78.48, and crystanillity 32.69%. The FT-IR spectra of snake fruit kernel CMC was similar with the CMC Standard.
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