四丁基氯化铵与rac -1,1′-双-2-萘酚配合物的晶体结构:表面活性剂分子被氢键双萘酚分子包裹

IF 0.1 Q4 CRYSTALLOGRAPHY X-ray Structure Analysis Online Pub Date : 2021-06-10 DOI:10.2116/XRAYSTRUCT.37.27
E. Marfo-owusu, A. Thompson
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引用次数: 0

摘要

阳离子。氢键网络的模式以及四n -烷基铵阳离子的构象有助于形成捕获BNP或四n -烷基铵阳离子的空隙。根据本研究揭示的知识,我们有动机研究TBAC和TPAC复合物与BNP的关系;(以下简称TBAC/BNP, TPAC/BNP),了解改变卤化物阴离子对填料模式和氢键网络的影响,并与TBAB/BNP和TPAB/BNP进行比较。在多次尝试获得这些复合物后,我们成功地只获得了TBAC/BNP复合物。四丁基氯化铵与rac -1,1′-双-2-萘酚配合物在单斜空间群p21 / n中结晶,单胞参数为;= 10.4941 (1) a、b = 26.3302 (3) a, c = 11.5290(1),α= 90°,β= 100.0154(5)°,γ= 90°,V = 3137.05 (5) 3, Z = 4。填充模式、氢键网络和晶体数据表明,晶体结构与报道的四丁基溴化铵与rac -1,1 ' -双-2-萘酚配合物的结构是同形的。2
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Crystal Structure of Tetrabutylammonium Chloride Complex with Rac-1,1′-bi-2-naphthol: The Inclusion of Surfactant Molecules by Hydrogen Bonded Binaphthol Molecules
cation. The patterns of the H-bond network as well as the conformation of the tetra- n -alkyl-ammonium cations contribute to the formation of voids that entrap either BNP or a tetra- n -alkylammonium cation. 2 Per the knowledge revealed in this study, we were motivated to investigate TBAC and TPAC complexes with BNP; (hereafter, TBAC/BNP, TPAC/BNP) in order to understand the effect of changing the halide anions on the packing modes as well as the H-bond network, and to compare with those in TBAB/BNP and TPAB/BNP. After several attempts to obtain these complexes, we were successful to obtain only a TBAC/BNP complex. The tetrabutylammonium chloride complex with rac -1,1 ′ -bi-2-naphthol crystallizes in monoclinic space group P 2 1 / n , with unit-cell parameters of; a = 10.4941(1)Å, b = 26.3302(3)Å, c = 11.5290(1)Å, α = 90 ° , β = 100.0154(5) ° , γ = 90 ° , V = 3137.05(5)Å 3 , and Z = 4. The packing mode, hydrogen bonding network, and crystal data suggest that the crystal structure is isomorphous with the reported structure of a tetrabutylammonium bromide complex with rac -1,1 ′ -bi-2-naphthol. 2
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CiteScore
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自引率
50.00%
发文量
17
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