约旦新鲜和冷冻鱼类中有机氯、有机磷、氨基甲酸酯类和拟除虫菊酯类农药残留量的测定和定量

A. Alaboudi, D. Almashhadany, B. S. Jarrah
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引用次数: 0

摘要

农药对水生系统的污染经常发生。本研究旨在检测约旦进口冷冻鱼和当地鲜鱼中有机氯、有机磷、拟除虫菊酯和氨基甲酸酯类杀虫剂的含量。随机抽取218份样本(其中194份为进口冷冻鱼)。采用液相色谱串联质谱法(LC/Ms/Ms)对样品进行分析。结果表明,本研究共检出23种不同的农药。所有218份鱼样本都被至少4种化合物和最多12种农药污染。在污染率方面,本地种类与进口种类并无显著差异。215个样本(98.6%)中,高达65.2%的农药浓度高于世界卫生组织规定的最大残留限量(10 ppb)。这些样本显示,进口或本地生产的产品均受到不同杀虫剂的严重污染。因此,官方要求对鱼类及其环境中的农药进行常规监测。
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Determination and Quantification of Some Organochlorines, Organophosphorus, Carbamates and Pyrethroids Pesticide Residues in Fresh and Frozen Fish in Jordan
Contamination of aquatic systems with pesticides occurs frequently. This study aimed to detect the levels of some pesticides: organochlorines, organophosphorus, pyrethroids, and carbamates groups in imported frozen and local fresh fish in Jordan. A total of 218 samples were randomly collected (194 imported frozen fish). Samples were analyzed using Liquid Chromatography with Tandem Mass Spectrometry (LC/Ms/Ms). Results showed that 23 different pesticides were found in this study. All 218 fish samples were contaminated with at least 4 compounds and maximally 12 pesticides. In terms of contamination rate, no significant differences between local and imported types were observed. Up to 65.2% of pesticides were detected at concentration higher than the maximum residue limit set by the WHO (10 ppb) in 215 samples (98.6%). These samples concluded heavy contaminations with different pesticides for either imported or locally raised products. Therefore, routine monitoring of pesticides in fish and their environment are officially required.
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