镁基金属有机骨架的环保合成与表征

Q4 Materials Science Journal of Surface Science and Technology Pub Date : 2023-02-15 DOI:10.18311/jsst/2021/28590
O. Lekshmy, K. S. Beena Kumari, R. Sudha Devi
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引用次数: 0

摘要

以苯二羧酸(BDC)、硫酸镁(MgSO4·7H2O)和虎耳草(Clitoria ternatea)花提取物为原料,合成了镁基金属有机骨架(MOF)。通过红外光谱、SEM-EDS、XRD、DLS和PL光谱对制备的MOF进行了表征。XRD图谱显示了合成的MOF的结晶性质。从SEM照片证实了MOF的纳米粒子性质。合成的Mg-MOF纳米粒子的FT-IR光谱在520cm-1处有一个峰,指定了其特征吸收带。ζ电位值表明,合成的MOF的表面电荷是中性的,因此分散在溶液中,在静置时没有任何团聚和凝结的趋势。光致发光光谱表明了发光性质,因此这种纳米晶体MOF作为发光材料和传感材料具有非常好的应用。
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Ecofriendly Synthesis and Characterization of Magnesium based Metal - Organic Frame Work
Magnesium based metal - organic Framework (MOF) was synthesized by using Benzene Di-Carboxylic acid (BDC), MgSO4.7H2O and a flower extract of Clitoria ternatea. The prepared MOF was characterized by FTIR spectrum, SEM-EDS, XRD, DLS and PL Spectrum. The crystalline nature of the synthesized MOF was revealed in XRD patterns. The nano particle nature of the MOF was confirmed from the SEM pictures. FT-IR spectra showed a peak at 520cm-1 designated characteristic absorption bands of synthesized Mg-MOF nano particles. The zeta potential value showed that the surface charge of the synthesized MOF is neutral and hence disperse in solution without having any tendency for agglomeration and coagulation on standing. The photoluminescence spectra indicated luminescent nature and hence this nano crystalline MOF finds very good application as luminescent material and as sensing material.
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期刊介绍: The Indian Society for Surface Science and Technology is an organization for the cultivation, interaction and dissemination of knowledge in the field of surface science and technology. It also strives to promote Industry-Academia interaction
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