几种水溶性药物在钢铁材料缓蚀中的回收利用:分析和电化学测量

Pub Date : 2021-04-01 DOI:10.15251/jobm.2021.132.45
R. A. Abdel Hameed, A. M. Al-bonayan
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引用次数: 17

摘要

过期的维生素B6药物的积累对我们的孩子和环境都有危害,本研究旨在将过期的水溶性药物以其药物形式重新用作1.0M HCl中石油管道制造商使用的钢合金的潜在无毒缓蚀剂。采用原子吸收光谱(AAS)和电化学技术对其缓蚀效果进行了评价,研究了浓度和温度对缓蚀效果的影响,结果表明,缓蚀效果随浓度的增加而增加,随温度的降低而降低。电位动力学极化数据显示,过期的维生素B6阻滞了阳极和阴极电位,这意味着它是一种混合抑制剂。电化学阻抗谱EIS,技术数据表明,过期药物通过吸附在金属/电解质界面上有助于提高极化电阻。发现这种吸附符合Langmuir吸附等温线模型。从所使用的技术中获得的数据与(±1)之间表现出良好的一致性,证明所使用的过期维生素B6药物在其制药中对酸性环境中的钢具有环保的缓蚀剂作用
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Recycling of Some Water Soluble Drugs for Corrosion Inhibition of Steel Materials: Analytical and Electrochemical Measurements
The accumulation of the expired vitamin B6 drugs is hazards for both our child’s and environment, the present research aimed to reuse the expired water soluble drug in its pharmaceutical form as potential non-toxic corrosion inhibitor for steel alloys used in manufacturer of the petroleum pipe lines in 1.0 M HCl. Atomic absorption spectroscopy(AAS) and electrochemical techniques were used to evaluate the corrosion inhibition efficiency, effect of concentrations and temperature were studied, the data show that the inhibition efficiency was increased with concentrations and decreased with temperature. Potentiodynamic polarization data show that the expired vitamin B6 retard both anodic and cathodic potential meaning it is a mixed inhibitor. The electrochemical impedance spectroscopy EIS, techniques data shows that the expired drug help to increases the polarization resistance by adsorbing on metal/electrolyte interface. This kind of adsorption found to obeying Langmuir adsorption isotherm model. The data obtained from the used techniques exhibit good agreement between them with (± 1) to prove that the used expired vitaminB6 medicinal drugs act as eco-friendly corrosion inhibitor for the steel in acidic environment in its pharmaceutical from
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