球磨负载铜锰氧化物的日本雪松炭的CO氧化性能

IF 0.1 4区 农林科学 Q4 MATERIALS SCIENCE, PAPER & WOOD Mokuzai Gakkaishi Pub Date : 2020-04-25 DOI:10.2488/jwrs.66.67
Yukuo Fujita, T. Takase, Takashi Asada
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摘要

在本工作中,使用以hopcalite为模型的Cu-Mn氧化物作为CO氧化催化剂。将Cu-Mn氧化物负载在日本雪松炭上,通过增加金属的活性面积来提高其CO氧化性能。在此,负载有Cu-Mn氧化物(CMC)的日本雪松炭如下制备。首先,使用球磨机将使用共沉淀法获得的Cu-Mn氧化物前体负载在日本雪松锯末上,然后将负载的锯末碳化。此外,还对CMC在富H2气体中氧化CO的性能进行了评价。催化剂活性的差异取决于用于样品制备的金属盐的类型、Cu和Mn的摩尔比以及碳化温度。CMC的CO氧化性能随着KMnO4的处理而提高。CMC处理后的H2浓度没有降低。因此,假设CMC可用作燃料电池的CO氧化催化剂。球磨机,负载型催化剂。
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CO Oxidation Performance of Japanese Cedar Charcoal Loaded with Copper-manganese Oxide Using a Ball Mill
In this work, the Cu-Mn oxide modeled on hopcalite is used as CO oxidation catalyst. The Cu-Mn oxide was loaded on Japanese cedar charcoal for improving its CO oxidation performance by increasing the active area of the metal. Herein, the Japanese cedar charcoal loaded with the Cu-Mn oxide (CMC) was prepared as follows. First, the Cu-Mn oxide precursor obtained using a coprecipitation method was loaded on Japanese cedar sawdust using a ball mill, and then this loaded sawdust was carbonized. Furthermore, the performance of the CMC for CO oxidation in H 2 -rich gas was evaluated. The difference in the catalyst activity was dependent on the types of metal salts used for the sample preparation, the molar ratio of Cu and Mn, and the carbonization temperature. The CO oxidation performance of the CMC increased with KMnO 4 treatment. The treated CMC did not reduce the concentration of H 2 . Hence, the CMC is assumed to be useful as a CO oxidation catalyst for a fuel cell. ball mill, supported catalyst.
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来源期刊
Mokuzai Gakkaishi
Mokuzai Gakkaishi 工程技术-材料科学:纸与木材
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20
审稿时长
>12 weeks
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