新型纳米结构镧镁铜锌锰矿的电物理性质

B. K. Kasenov
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引用次数: 0

摘要

通过镧(III)、铜(II)、锌(II)和锰(III)以及碳酸镁的氧化物在800-1200°C范围内的固相相互作用合成了多晶铜锌锰酸盐,从而首次在振动磨机“Retsch”(德国)上研磨获得了其纳米结构颗粒。X射线研究确定纳米结构的锰酸盐在立方合成气中结晶。在LCR-7817/827器件(公司«Good Will Instrument Co.,有限公司,台湾»)上,在293-483K范围内,在等于1.5和10kHz的频率下,研究了介电常数和电阻,发现该化合物在293-353K下具有半导电性,在353-373K下为金属,在373-483K下再次具有半导体导电性。计算了带隙宽度。483K的介电常数在所有频率下都达到了巨大的值。参考以上内容,本文的目的是研究一种新的镧和镁纳米结构铜锌锰酸盐的介电常数和电阻的温度依赖性。
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ELECTROPHYSICAL PROPERTIES OF NEW NANOSTRUCTURED COPPER-ZINC MANGANITE OF LANTHANUM AND MAGNESIUM
The polycrystalline copper-zinc manganite was synthesized by the solid-phase interaction in the range of 800-1200 °C of oxides of lanthanum (III), copper (II), zinc (II), manganese (III) and magnesium carbonate, thus its nanostructured particles were first obtained by grinding on the vibrating mill “Retsch” (Germany). The X-ray investigations determined that the nanostructured manganite is crystallized in the cubic syngony. On the LCR-7817/827 device(Company «Good Will Instrument Co., Ltd., Taiwan») in the range of 293-483 K at frequencies equal to 1.5 and 10 kHz, the dielectric constantand electrical resistance were investigated and it was found that this compound at 293-353 K has the semiconductorconductivity, at 353-373 K -metal and at 373-483 K -semiconductor conductivity again. The band gap widths were calculated. The permittivity at 483 K reaches gigantic values at all frequencies.Referring to the above, the objective of this paper is to study the temperature dependence of the dielectric constantand the electrical resistance of a new nanostructured copper-zinc manganite of lanthanum and magnesium.
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