D. Volkov, E. Glazunova, L. Shilkina, Aleksandr V. Nazarenko, A. Pavelko, Vyacheslav A. Bobylev, L. Reznichenko, I. A. Verbenko
{"title":"基于Ba(Ti, Zr)O3和AgNbO3的环境友好型高效储能多组分固溶体的相形成和性能","authors":"D. Volkov, E. Glazunova, L. Shilkina, Aleksandr V. Nazarenko, A. Pavelko, Vyacheslav A. Bobylev, L. Reznichenko, I. A. Verbenko","doi":"10.3390/ceramics6030112","DOIUrl":null,"url":null,"abstract":"This paper investigates the processes of phase formation of solid solutions of (1 − x)BaTi0.85Zr0.15O3 − xAgNbO3 where x = 0, 0.03, 0.06, 0.09. The optimal temperatures of synthesis and sintering are determined. From the results of X-ray diffraction analysis, it follows that all solid solutions have a perovskite-type structure. Analysis of the microstructure showed that the average grain size decreases at concentrations x = 0.03 and 0.06. Correlations between the cationic composition and dielectric characteristics of the studied solid solutions have been established. The values of the total stored energy and efficiency are determined. The maximum stored energy was found for a solid solution with x = 0.03 and amounted to 0.074 J∙cm−3 with an efficiency of 76.5%.","PeriodicalId":33263,"journal":{"name":"Ceramics-Switzerland","volume":" ","pages":""},"PeriodicalIF":2.7000,"publicationDate":"2023-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Phase Formation and Properties of Multicomponent Solid Solutions Based on Ba(Ti, Zr)O3 and AgNbO3 for Environmentally Friendly High-Efficiency Energy Storage\",\"authors\":\"D. Volkov, E. Glazunova, L. Shilkina, Aleksandr V. Nazarenko, A. Pavelko, Vyacheslav A. Bobylev, L. Reznichenko, I. A. Verbenko\",\"doi\":\"10.3390/ceramics6030112\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This paper investigates the processes of phase formation of solid solutions of (1 − x)BaTi0.85Zr0.15O3 − xAgNbO3 where x = 0, 0.03, 0.06, 0.09. The optimal temperatures of synthesis and sintering are determined. From the results of X-ray diffraction analysis, it follows that all solid solutions have a perovskite-type structure. Analysis of the microstructure showed that the average grain size decreases at concentrations x = 0.03 and 0.06. Correlations between the cationic composition and dielectric characteristics of the studied solid solutions have been established. The values of the total stored energy and efficiency are determined. The maximum stored energy was found for a solid solution with x = 0.03 and amounted to 0.074 J∙cm−3 with an efficiency of 76.5%.\",\"PeriodicalId\":33263,\"journal\":{\"name\":\"Ceramics-Switzerland\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2023-08-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ceramics-Switzerland\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3390/ceramics6030112\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics-Switzerland","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/ceramics6030112","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Phase Formation and Properties of Multicomponent Solid Solutions Based on Ba(Ti, Zr)O3 and AgNbO3 for Environmentally Friendly High-Efficiency Energy Storage
This paper investigates the processes of phase formation of solid solutions of (1 − x)BaTi0.85Zr0.15O3 − xAgNbO3 where x = 0, 0.03, 0.06, 0.09. The optimal temperatures of synthesis and sintering are determined. From the results of X-ray diffraction analysis, it follows that all solid solutions have a perovskite-type structure. Analysis of the microstructure showed that the average grain size decreases at concentrations x = 0.03 and 0.06. Correlations between the cationic composition and dielectric characteristics of the studied solid solutions have been established. The values of the total stored energy and efficiency are determined. The maximum stored energy was found for a solid solution with x = 0.03 and amounted to 0.074 J∙cm−3 with an efficiency of 76.5%.
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