负载在SiO2上的P2O5作为一种高效且可重复使用的催化剂在无溶剂条件下快速一锅合成氨基甲酸烷基萘酚

Atefeh Ghasemi, A. Davoodnia, M. Pordel, N. Tavakoli-Hoseini
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引用次数: 3

摘要

摘要在SiO2负载P2O5 (P2O5/SiO2)存在下,在温和条件下,无需添加任何有机溶剂,β-萘酚与多种芳醛和氨基甲酸甲酯进行了一锅三组分反应,合成了氨基甲酸烷烷基萘酚。结果表明,该催化剂活性高,反应时间短,产率高。该工艺的其他优点还包括催化剂价格低廉,易于获得,操作简单,催化剂可连续循环使用5次。
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P2O5 supported on SiO2 as an efficient and reusable catalyst for rapid one-pot synthesis of carbamatoalkyl naphthols under solvent-free conditions
Abstract Under mild conditions and without any additional organic solvent, synthesis of carbamatoalkyl naphthols by the one-pot three-component reaction of β-naphthol with a wide range of aromatic aldehydes and methyl carbamate could be carried out in the presence of P2O5 supported on SiO2 (P2O5/SiO2). The results showed that the catalyst has high activity and the desired products were obtained in high yields in short reaction times. Other beneficial features of this protocol include inexpensive and easily obtained catalyst, simple work-up, and the recyclability and reusability of the catalyst for up to five consecutive runs.
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Cogent Chemistry
Cogent Chemistry CHEMISTRY, MULTIDISCIPLINARY-
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