添加硅藻土粉对工业废粉煤灰基地聚合物机械强度、耐高温性能和微观结构性能的影响

IF 2.7 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Journal of Material Cycles and Waste Management Pub Date : 2023-05-12 DOI:10.1007/s10163-023-01692-x
Ahmet Özsoy, Ezgi Örklemez, Serhan İlkentapar
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引用次数: 2

摘要

本研究考察了在生产可持续地聚合物粘合剂中,粉煤灰(一种火力发电厂废物)的使用,以及硅藻土(一种化石藻类类型)对基于废物的地聚合物的影响。研究了1%、2%、3%、4%和5%硅藻土替代废基砂浆的效果。以含10%和12%重量Na+的粘结剂材料为基础,在75℃下固化48 h。研究了地聚合物砂浆样品的抗折强度、抗压强度、耐磨性、超声脉冲速度测定和耐高温性能。此外,对地聚合物砂浆样品进行了FESEM、EDX和XRD分析,并对其微观结构进行了表征。2%硅藻土替代提高了抗弯和抗压强度。与此同时,添加2%硅藻土的地聚合物砂浆的耐磨性和超声脉冲速度均有所提高。此外,FESEM图像显示,微观结构具有致密的形态。在300℃、600℃和900℃的高温下,所有地聚合物砂浆都失去了强度。结果表明,含高活性二氧化硅的硅藻土可用于地聚合物体系。
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Effect of addition diatomite powder on mechanical strength, elevated temperature resistance and microstructural properties of industrial waste fly ash-based geopolymer

This study examines the use of fly ash, a thermal power plant waste, and the effect of diatomite, a fossil algae type, on waste-based geopolymers in the production of sustainable geopolymer binders. The effects of 1%, 2%, 3%, 4% and, 5% diatomite substitution on waste-based mortars were investigated. Mortars containing 10% and 12% Na+ by weight based on the binder material were cured at 75 °C for 48 h. The flexural and compressive strength, abrasion resistance, determination of ultrasonic pulse velocity, and resistance to high temperatures of geopolymer mortar samples were investigated. In addition, FESEM images, EDX and XRD analyses of geopolymer mortar samples were made, and their microstructures were examined. 2% diatomite substitution increased flexural and compressive strength. In parallel with this situation, it was concluded that the abrasion resistance and ultrasonic pulse velocity of the geopolymer mortar with 2% diatomite substituted increased. In addition, it has been shown in FESEM images that the microstructure has a denser morphology. All geopolymer mortars lost strength after the high temperatures of 300 °C, 600 °C and 900 °C. As a result, it was concluded that diatomite containing highly reactive silica can be used in geopolymer systems.

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来源期刊
CiteScore
5.30
自引率
16.10%
发文量
205
审稿时长
4.8 months
期刊介绍: The Journal of Material Cycles and Waste Management has a twofold focus: research in technical, political, and environmental problems of material cycles and waste management; and information that contributes to the development of an interdisciplinary science of material cycles and waste management. Its aim is to develop solutions and prescriptions for material cycles. The journal publishes original articles, reviews, and invited papers from a wide range of disciplines related to material cycles and waste management. The journal is published in cooperation with the Japan Society of Material Cycles and Waste Management (JSMCWM) and the Korea Society of Waste Management (KSWM).
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