{"title":"利用石墨烯纳米片的特性提高橡胶纳米复合材料的交联密度","authors":"H. S. Majdi, L. Habeeb","doi":"10.22052/JNS.2020.04.005","DOIUrl":null,"url":null,"abstract":"Graphene nanoplatelets (GNP) / Acrylonitrile butadiene rubber (NBR) nanocomposites were prepared by solutions mixing method and vulcanized effectively. GNP suspension dispersed homogenously in a well-suited solution of NBR up to 2.4 phr and characterized by X-ray Diffraction (XRD). The influence of GNP on the cross-linking of GNP/NBR nanocomposites structure has been characterized and studied by the cure characteristics and swelling tests. The results showed that the cross-linking density was enhanced to 42.3% compared to that of unfilled NBR by reducing the swelling ratio to 19.7% at 1.2 phr of the GNP. Thus, the mechanical properties were investigated and revealed that the modulus at 100% elongation (M100) improved to about 155% and the hardness to about 13%. Those results were verified via the morphology analyzing using Scanning Electron Microscopy (SEM) and the enhancement of the storage modulus as a function of temperature in the rubber nanocomposite to about 100% utilizing Dynamic Mechanical Analysis (DMA) at the same content 1.2 phr of GNP.","PeriodicalId":16523,"journal":{"name":"Journal of Nanostructures","volume":"10 1","pages":"723-735"},"PeriodicalIF":1.4000,"publicationDate":"2020-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Utilizing the Characteristics of Graphene Nano-Platelets to Improve the Cross-Linking Density of a Rubber Nano-Composite\",\"authors\":\"H. S. Majdi, L. Habeeb\",\"doi\":\"10.22052/JNS.2020.04.005\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Graphene nanoplatelets (GNP) / Acrylonitrile butadiene rubber (NBR) nanocomposites were prepared by solutions mixing method and vulcanized effectively. GNP suspension dispersed homogenously in a well-suited solution of NBR up to 2.4 phr and characterized by X-ray Diffraction (XRD). The influence of GNP on the cross-linking of GNP/NBR nanocomposites structure has been characterized and studied by the cure characteristics and swelling tests. The results showed that the cross-linking density was enhanced to 42.3% compared to that of unfilled NBR by reducing the swelling ratio to 19.7% at 1.2 phr of the GNP. Thus, the mechanical properties were investigated and revealed that the modulus at 100% elongation (M100) improved to about 155% and the hardness to about 13%. Those results were verified via the morphology analyzing using Scanning Electron Microscopy (SEM) and the enhancement of the storage modulus as a function of temperature in the rubber nanocomposite to about 100% utilizing Dynamic Mechanical Analysis (DMA) at the same content 1.2 phr of GNP.\",\"PeriodicalId\":16523,\"journal\":{\"name\":\"Journal of Nanostructures\",\"volume\":\"10 1\",\"pages\":\"723-735\"},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2020-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Nanostructures\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.22052/JNS.2020.04.005\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"NANOSCIENCE & NANOTECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Nanostructures","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.22052/JNS.2020.04.005","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"NANOSCIENCE & NANOTECHNOLOGY","Score":null,"Total":0}
Utilizing the Characteristics of Graphene Nano-Platelets to Improve the Cross-Linking Density of a Rubber Nano-Composite
Graphene nanoplatelets (GNP) / Acrylonitrile butadiene rubber (NBR) nanocomposites were prepared by solutions mixing method and vulcanized effectively. GNP suspension dispersed homogenously in a well-suited solution of NBR up to 2.4 phr and characterized by X-ray Diffraction (XRD). The influence of GNP on the cross-linking of GNP/NBR nanocomposites structure has been characterized and studied by the cure characteristics and swelling tests. The results showed that the cross-linking density was enhanced to 42.3% compared to that of unfilled NBR by reducing the swelling ratio to 19.7% at 1.2 phr of the GNP. Thus, the mechanical properties were investigated and revealed that the modulus at 100% elongation (M100) improved to about 155% and the hardness to about 13%. Those results were verified via the morphology analyzing using Scanning Electron Microscopy (SEM) and the enhancement of the storage modulus as a function of temperature in the rubber nanocomposite to about 100% utilizing Dynamic Mechanical Analysis (DMA) at the same content 1.2 phr of GNP.
期刊介绍：
Journal of Nanostructures is a medium for global academics to exchange and disseminate their knowledge as well as the latest discoveries and advances in the science and engineering of nanostructured materials. Topics covered in the journal include, but are not limited to the following: Nanosystems for solar cell, energy, catalytic and environmental applications Quantum dots, nanocrystalline materials, nanoparticles, nanocomposites Characterization of nanostructures and size dependent properties Fullerenes, carbon nanotubes and graphene Self-assembly and molecular organization Super hydrophobic surface and material Synthesis of nanostructured materials Nanobiotechnology and nanomedicine Functionalization of nanostructures Nanomagnetics Nanosensors.
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