改性MgO晶须对油浸单体铸造尼龙力学和摩擦学性能的影响

IF 1 4区 化学 Q4 POLYMER SCIENCE Polymer Science, Series B Pub Date : 2023-06-13 DOI:10.1134/S1560090423700963
Yaxuan Zhu, Yuxin Wang, Yuexin Wang, Gang Liu, Qian Zhang
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引用次数: 1

摘要

氧化镁晶须是常用的聚合物增强材料。本研究首先采用γ-氨基丙基三乙氧基硅烷和N,N′-羰基二咪唑活化的正十八胺对氧化镁晶须进行改性。然后将改性氧化镁晶须引入到油浸单体铸造尼龙中。通过原位聚合得到最终的复合材料。研究了改性氧化镁晶须含量不同的复合材料的力学性能和摩擦学性能。结果表明,复合材料的拉伸强度、弯曲强度、断裂伸长率和冲击强度均有明显提高,力学性能和摩擦学性能均有明显改善。摩擦学试验结果表明,摩擦系数降低,磨损损失减小。复合材料的表面亲脂性也明显提高。本工作为设计具有优异力学和摩擦性能的复合材料提供了一种简单的方法,可极大地拓展复合材料的应用潜力。
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Effect of Modified MgO Whisker on Mechanical and Tribological Properties of Oil-Impregnated Monomer Casting Nylon

The magnesium oxide whisker was commonly used as reinforcement for polymer. In this study, magnesium oxide whisker was firstly modified by γ-aminopropyl triethoxysilane and n-octadecylamine activated by N,N'-carbonyldiimidazole. Then the modified magnesium oxide whisker was introduced into oil-impregnated monomer casting nylon. The final composite was obtained by in situ polymerization. The mechanical and tribological properties of composite with different contents of modified magnesium oxide whisker were investigated. The results showed that the mechanical and tribological performances of the composites were observably improved by growth of tensile strength, flexural strength, elongation at break, and impact strength. The tribological test results indicated that reduction in the frictional coefficient and the abrasion loss was achieved. The surface lipophilicity of composites obviously increased also. This work provided a simple method for designing composites with excellent mechanical and frictional properties which may greatly broaden the application potential of composites.

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来源期刊
Polymer Science, Series B
Polymer Science, Series B 化学-高分子科学
CiteScore
1.80
自引率
8.30%
发文量
58
审稿时长
>0 weeks
期刊介绍: Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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