摘要由羧酸配体衍生的金属有机骨架(MOFs)作为修复水溶液中Cu (II)和Pb (II)的潜在材料

H. Okoro, Oluwaseyi Ayika, A. Tella, J. Ngila
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引用次数: 2

摘要

使用由铜和锌与苯-1,4-二羧酸(BDC)开发的金属有机骨架(MOFs),从各自的水溶液中修复镉和铅离子。实验吸附过程是分批进行的,以确定吸附过程的平衡特性、热力学和动力学。然后使用Langmuir、Freundlich和Temkin等温线方程对结果进行测试,Langmuir是拟合最好的等温线,而所使用的动力学等温线是伪一阶和伪二阶。结果表明,MOFs对所研究的金属具有很大的吸附潜力。
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METAL-ORGANIC FRAMEWORKS (MOFs) DERIVED FROM CARBOXYLATE LIGAND AS POTENTIAL MATERIALS FOR REMEDIATION OF Cu (II) AND Pb (II) FROM AQUEOUS SOLUTION
The remediation of cadmium and lead ions from their respective aqueous solutions was carried out with the use of metal-organic frameworks (MOFs) developed from copper and zinc with benzene-1,4-dicarboxylic acid (BDC). The experimental adsorption process was done in batches to determine the equilibrium characteristics, thermodynamics and kinetics of the sorption processes. The result was then tested using Langmuir, Freundlich, and Temkin isotherm equations with Langmuir being the best fitted isotherm, while the kinetics isotherm used were pseudo first order and pseudo second order. The result obtained shows that the MOFs are great potential adsorbent for the studied metals.
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来源期刊
CiteScore
1.60
自引率
0.00%
发文量
81
审稿时长
5 weeks
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