来自尼日利亚西南部Ile-Ife的玻璃制造坩埚

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2018-08-01 DOI:10.1163/21915784-20180002
A. B. Babalola, T. Rehren, A. Ige, S. McIntosh
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引用次数: 30

摘要

在撒哈拉以南非洲的考古环境中,用于熔化玻璃的坩埚非常罕见。最近在伊莱- ife(尼日利亚西南部)的伊博·奥洛肯(Igbo Olokun)进行的考古发掘发现了公元11 -15世纪沉积物中大量的玻璃坩埚碎片,与之前在伊莱- ife报道的完整和近乎完整的例子相匹配。本文对这些坩埚碎片进行了深入的研究,以了解坩埚的材料质量,它们的类型以及它们在玻璃加工/制造中的功能。对10个坩埚试样进行了光学显微镜、扫描电镜和能谱分析。介绍了陶瓷织物的组成和粘接玻璃的功能,并对其进行了讨论。坩埚是由特别挑选的高耐火粘土制成的,用于从原材料中熔化玻璃;在坩埚中的熔体中加入了着色剂。坩埚的可用容量从1升到7升不等,相当于每个坩埚约2.5至17.5公斤成品玻璃。对挖掘出的数千个玻璃珠样本的成分分析表明,坩埚是用来熔化玻璃珠的。这种规模的玻璃珠制作的考古证据以前从未在西非报道过。这些坩埚是撒哈拉以南非洲地区从公元第二个千年早期到中期土著玻璃加工/制造的独特证据。
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The Glass Making Crucibles from Ile-Ife, SW Nigeria
Crucibles to melt glass are very rare in archaeological contexts in sub-Saharan Africa. Recent archaeological excavations at Igbo Olokun, Ile-Ife (Southwest Nigeria) revealed abundant fragments of glass crucibles from 11th-15th century AD deposits, matching the complete and near complete examples earlier reported from Ile-Ife. This paper provides an in-depth examination of these crucible fragments in order to understand the material quality of the crucibles, their typology, and their functions in glass- working/making. Optical microscopic and scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS) analyses were carried out on ten crucible samples. The composition of ceramic fabrics and the adhering glass are presented and discussed in view of their function. The crucibles were produced from specifically selected highly refractory clay and used for melting glass from its raw materials; colorants were added to the melt in the crucible. The useable capacity of the crucibles varied from 1 to 7 liters, equivalent to about 2.5 to 17.5 kg of finished glass for each crucible. Compositional analysis of a sample of the thousands of glass beads from the excavations indicates that the crucibles were used to melt the glass used in the beads. Archaeological evidence of glass bead making at this scale has not previously been reported from West Africa. The crucibles are unique evidence of indigenous glass-working/making in Sub-Saharan Africa from early through mid-second millennium AD.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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