O. I. Kalchenko, S. O. Cherenok, O. M. Silenko, V. I. Kalchenko
{"title":"氨基酸性质对杯芳烃亚甲基-双膦酸形成超分子配合物的影响","authors":"O. I. Kalchenko, S. O. Cherenok, O. M. Silenko, V. I. Kalchenko","doi":"10.1007/s11237-022-09742-5","DOIUrl":null,"url":null,"abstract":"<div><div><p>The formation of supramolecular complexes of 3-methyl-sulfido-propoxycalix[4]arene-methylene-<i>bis</i>-phosphonic acid with seventeen amino acids in aqueous solutions has been studied and their stability coefficients have been determined by the method of high-performance liquid chromatography. The structures of the supramolecular complexes have been proposed by molecular modeling and the influence of structural factors (the stabilization of different conformations of the obtained complexes depending on amino acid nature: possibilities of the realization of hydrogen bonds and electrostatic interactions between different groups of the amino acids and calixarene) on the stability of the supramolecules has been shown.</p></div></div>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":"58 4","pages":"254 - 260"},"PeriodicalIF":0.7000,"publicationDate":"2022-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of the Nature of Amino Acids on the Formation of Supramolecular Complexes with Calixarenemethylene-bis-Phosphonic Acid\",\"authors\":\"O. I. Kalchenko, S. O. Cherenok, O. M. Silenko, V. I. Kalchenko\",\"doi\":\"10.1007/s11237-022-09742-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div><p>The formation of supramolecular complexes of 3-methyl-sulfido-propoxycalix[4]arene-methylene-<i>bis</i>-phosphonic acid with seventeen amino acids in aqueous solutions has been studied and their stability coefficients have been determined by the method of high-performance liquid chromatography. The structures of the supramolecular complexes have been proposed by molecular modeling and the influence of structural factors (the stabilization of different conformations of the obtained complexes depending on amino acid nature: possibilities of the realization of hydrogen bonds and electrostatic interactions between different groups of the amino acids and calixarene) on the stability of the supramolecules has been shown.</p></div></div>\",\"PeriodicalId\":796,\"journal\":{\"name\":\"Theoretical and Experimental Chemistry\",\"volume\":\"58 4\",\"pages\":\"254 - 260\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2022-12-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Theoretical and Experimental Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11237-022-09742-5\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical and Experimental Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11237-022-09742-5","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Influence of the Nature of Amino Acids on the Formation of Supramolecular Complexes with Calixarenemethylene-bis-Phosphonic Acid
The formation of supramolecular complexes of 3-methyl-sulfido-propoxycalix[4]arene-methylene-bis-phosphonic acid with seventeen amino acids in aqueous solutions has been studied and their stability coefficients have been determined by the method of high-performance liquid chromatography. The structures of the supramolecular complexes have been proposed by molecular modeling and the influence of structural factors (the stabilization of different conformations of the obtained complexes depending on amino acid nature: possibilities of the realization of hydrogen bonds and electrostatic interactions between different groups of the amino acids and calixarene) on the stability of the supramolecules has been shown.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
