聚合硅酸氯化铝混凝剂去除镍的效果研究

M. Mohammadi, A. Takdastan, Mehdi Zhoolanezhad, A. Neisi
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引用次数: 0

摘要

背景与目的:镍是通过工业活动自然释放到环境中的有毒重金属之一。混凝絮凝是一种有效的重金属去除方法,但经验表明,混凝絮凝工艺去除镍通常需要高pH值和添加助凝剂。本研究旨在考察聚硅酸铝-氯化铝(PASiC)混凝剂对水溶液中镍的去除效率。材料和方法:本研究采用标准罐试验方法在实验室规模上进行实验。我们研究了pH参数(4-11)、混凝剂的量(基于铝为7.5-75mg/L)、初始金属浓度(10-400mg/L)和沉淀时间(15-90分钟)的影响。用火焰原子吸收光谱法测定了镍的浓度。本研究采用t检验、组间方差分析和回归分析方法进行分析。结果:结果表明,金属镍浓度越高,去除率越低。此外,将沉淀时间增加到30分钟以上并没有显著改变去除效率。在最佳pH为8、最佳PASiC浓度为15mg/L、最佳时间为30分钟、镍浓度为10-100mg/L的条件下,PASiC的去除率超过99%。结论:PASiC作为混凝剂是一种较好的除镍方法。
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The Efficiency of Polyaluminum Silicate Chloride Coagulants in Nickel Removal from Aqueous Solutions
Background & Aims: Nickel is one of the toxic heavy metals naturally released into the environment through industrial activities. Coagulation and flocculation are one of the available heavy metal removal methods, but experience has shown that high pH and the addition of coagulant aid are usually required to remove nickel by coagulation and flocculation process. This study aimed to examine the efficiency of polyaluminum silicate chloride (PASiC) coagulant in nickel removal from aqueous solutions. Materials and Methods: This study was conducted experimentally on a laboratory scale using the standard jar testing method. We investigated the effect of pH parameters (4-11), amount of coagulant (7.5-75 mg/L based on aluminum), initial metal concentration (10-400 mg/L), and settling time (15-90 minutes). Nickel concentration was measured by flame atomic absorption spectroscopy. In this study, t test, between-groups ANOVA, and regression were used for analysis. Results: Results showed that the removal efficiency decreased at higher concentrations of nickel metal. Furthermore, increasing the settling time beyond 30 minutes did not significantly change the removal efficiency. PASiC had a removal efficiency of over 99% at an optimum pH of 8, an optimum PASiC concentration of 15 mg/L, an optimum time of 30 minutes, and a nickel concentration of 10-100 mg/L. Conclusion: According to the results, the use of PASiC as a coagulant is a suitable option for removing nickel from polluted wastewater.
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