Liping Tan , Yamei Sun , Changjun Yang , Bingguang Zhang , Kejian Deng , Xiaofeng Cao , Yanchuan Guo
{"title":"ZnO/Fe硫代卟啉复合材料作为高效光催化剂在水中氧化甘油生成附加值C3产物","authors":"Liping Tan , Yamei Sun , Changjun Yang , Bingguang Zhang , Kejian Deng , Xiaofeng Cao , Yanchuan Guo","doi":"10.1016/j.mcat.2023.112972","DOIUrl":null,"url":null,"abstract":"<div><p>Photocatalytic selective oxidation of glycerol to value-added C<sub>3</sub><span> products is a promising strategy for the valorization of glycerol. In this work, an inorganic/organic composite material by integrating zinc oxide (ZnO) with iron thioporphyrazine (FePz) was prepared to act as photocatalyst for photocatalytic oxidation of glycerol in water. The effects of FePz surface modification on the physicochemical properties and photocatalytic performance of ZnO<span> were systemically studied. More importantly, the integration of ZnO with FePz could markedly improve the visible light absorption ability and effectively promote the separation of photogenerated charges. Meanwhile, introducing FePz onto the ZnO surface was beneficial to the adsorption capacity of glycerol. Just because of this, ZnO/FePz composite exhibited excellent photocatalytic activity for oxidizing glycerol in water, C</span></span><sub>3</sub> products including glyceraldehyde and dihydroxyacetone were obtained from this composite photocatalytic system. Additionally, the active species responsible for glycerol oxidation were also determined.</p></div>","PeriodicalId":393,"journal":{"name":"Molecular Catalysis","volume":null,"pages":null},"PeriodicalIF":3.9000,"publicationDate":"2023-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"ZnO/Fe-thioporphyrazine composites as efficient photocatalysts for oxidation of glycerol to value-added C3 products in water\",\"authors\":\"Liping Tan , Yamei Sun , Changjun Yang , Bingguang Zhang , Kejian Deng , Xiaofeng Cao , Yanchuan Guo\",\"doi\":\"10.1016/j.mcat.2023.112972\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Photocatalytic selective oxidation of glycerol to value-added C<sub>3</sub><span> products is a promising strategy for the valorization of glycerol. In this work, an inorganic/organic composite material by integrating zinc oxide (ZnO) with iron thioporphyrazine (FePz) was prepared to act as photocatalyst for photocatalytic oxidation of glycerol in water. The effects of FePz surface modification on the physicochemical properties and photocatalytic performance of ZnO<span> were systemically studied. More importantly, the integration of ZnO with FePz could markedly improve the visible light absorption ability and effectively promote the separation of photogenerated charges. Meanwhile, introducing FePz onto the ZnO surface was beneficial to the adsorption capacity of glycerol. Just because of this, ZnO/FePz composite exhibited excellent photocatalytic activity for oxidizing glycerol in water, C</span></span><sub>3</sub> products including glyceraldehyde and dihydroxyacetone were obtained from this composite photocatalytic system. Additionally, the active species responsible for glycerol oxidation were also determined.</p></div>\",\"PeriodicalId\":393,\"journal\":{\"name\":\"Molecular Catalysis\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.9000,\"publicationDate\":\"2023-02-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Molecular Catalysis\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2468823123000597\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Molecular Catalysis","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2468823123000597","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
ZnO/Fe-thioporphyrazine composites as efficient photocatalysts for oxidation of glycerol to value-added C3 products in water
Photocatalytic selective oxidation of glycerol to value-added C3 products is a promising strategy for the valorization of glycerol. In this work, an inorganic/organic composite material by integrating zinc oxide (ZnO) with iron thioporphyrazine (FePz) was prepared to act as photocatalyst for photocatalytic oxidation of glycerol in water. The effects of FePz surface modification on the physicochemical properties and photocatalytic performance of ZnO were systemically studied. More importantly, the integration of ZnO with FePz could markedly improve the visible light absorption ability and effectively promote the separation of photogenerated charges. Meanwhile, introducing FePz onto the ZnO surface was beneficial to the adsorption capacity of glycerol. Just because of this, ZnO/FePz composite exhibited excellent photocatalytic activity for oxidizing glycerol in water, C3 products including glyceraldehyde and dihydroxyacetone were obtained from this composite photocatalytic system. Additionally, the active species responsible for glycerol oxidation were also determined.
期刊介绍:
Molecular Catalysis publishes full papers that are original, rigorous, and scholarly contributions examining the molecular and atomic aspects of catalytic activation and reaction mechanisms. The fields covered are:
Heterogeneous catalysis including immobilized molecular catalysts
Homogeneous catalysis including organocatalysis, organometallic catalysis and biocatalysis
Photo- and electrochemistry
Theoretical aspects of catalysis analyzed by computational methods