碱压蒸汽法制备甜高粱秸秆纤维复合增强剂

E. Yuanita, H. Adi, I. Ismojo, M. Mochtar, M. Chalid
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引用次数: 1

摘要

全球越来越关注与保护不可再生自然资源有关的环境问题和可持续性,这鼓励了基于可再生自然资源开发新的环保材料和产品的研究。高粱纤维具有良好的力学性能、环保性和廉价性,有可能成为一种复合增强材料。高粱纤维的制备工艺需要改善其与聚丙烯(PP)的相容性。热碱化是导电纤维制备中使用的一种方法。在本研究中,用0%、5%和10%的NaOH和加压蒸汽进行了1和3分钟的碱化热处理,以改变高粱纤维的疏水性。在5%NaOH浓度下,压力浸泡3分钟,获得了最佳结果,基于FESEM测试,显示出更清洁和原纤维化的形态。FTIR测试结果表明,它的木质素和半纤维素含量较低,Session-Drop测试结果表明其疏水性较好,接触角为120.9◦, 以及如X射线衍射(XRD)测试结果所示的结晶度指数显著增加6.3%。改性高粱纤维疏水性的提高表明天然纤维与聚合物基体的相容性提高。
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Preparation of Composite Reinforced Agent Based on Sweet Sorghum Stalk Fiber through Alkali Pressure Steam Treated Method
Increasing global concern to environmental issues and sustainability related to preservation of non-renewable natural resources has encouraged research to develop new environmental friendly materials and products based on renewable natural resources. Sorghum fiber has potential to be a composite reinforcement because it has a good mechanical properties, environmental friendly and inexpensive. The preparation process of sorghum fiber is needed to improve its compatibility with polypropylene (PP). Thermal alkalization is the method used in conducting fiber preparation. In this study, alkalization-thermal treatment with 0%, 5% and 10% NaOH and pressurized steam for 1 and 3 minutes was carried out to change the hydrophobicity of sorghum fiber. The most optimum result was obtained at 5% NaOH concentration with 3 minutes pressure-soaking, showing cleaner and fibrillated morphology based on FESEM testing. It was less lignin and hemicellulose content as indicated by FTIR testing result, better hydrophobicity as indicated through Sessil Drop testing result that showed contact angle of 120.9◦, as well as significant increase in crystallinity index of 6.3% as indicated through X-Ray Diffraction (XRD) test result. The increase in the hydrophobicity of the modified sorghum fiber indicated the increase of the natural fiber compatibility with polymer matrix.
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