DCH18C6利用锶提取选择性研究和土壤连续分级研究

Q4 Agricultural and Biological Sciences Nova Biotechnologica et Chimica Pub Date : 2022-01-13 DOI:10.36547/nbc.1364
Gabriela Pisarčíková, L. Závodsḱa, J. Lesńy
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引用次数: 0

摘要

以85Sr为放射性指示剂,以顺式二环己基18-冠-6(DCH18C6)为萃取剂,苦味酸为反离子,对锶的分离选择性进行了研究,为快速提取锶方法的发展做出了贡献。通过应用Tessier-和BCR顺序提取程序,已将相同的放射性指示剂用于选定土壤中的锶分馏研究。实验结果表明,上述提取系统适用于IDA测定Ca2+丰度~1000倍、Mg2+丰度~1000多倍、K+丰度~10倍和Ba2+丰度~0.2倍的Sr2+。对于来自JaslovskéBohunice核电站附近的土壤样本(黄土上发育的黑钙土),可交换锶含量高达50-60%。
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DCH18C6 using strontium extraction selectivity investigation and sequential soil fractionation study
85Sr as radioindicator has been applied to strontium separation selectivity study using cisdicyclohexano-18-crown-6 (DCH18C6) as extraction agent and picric acid as counter ion with the aim to contribute to the development of a rapid method of strontium extraction. The same radioindicator has been used for strontium fractionation study in chosen soils by application of Tessier- and BCR sequential extraction procedures. Experimental results have shown, that the mentioned extraction system is applicable for IDA determination of Sr2+ in ∼1000-fold abundance of Ca2+, ∼1000-fold abundance and Mg2+, ∼10-fold abundance of K+ and ∼0.2-fold abundance of Ba2+. For the soil samples - chernozems developed on loess - from the near vicinity of NPP Jaslovské Bohunice the exchangeable strontium fraction reached as much as 50 – 60 %.
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来源期刊
Nova Biotechnologica et Chimica
Nova Biotechnologica et Chimica Agricultural and Biological Sciences-Food Science
CiteScore
0.60
自引率
0.00%
发文量
47
审稿时长
24 weeks
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