镍掺杂TiO2纳米粒子包埋堇叶Tinospora植物降解孔雀石绿染料

IF 3.3 Q3 NANOSCIENCE & NANOTECHNOLOGY Nanofabrication Pub Date : 2023-07-27 DOI:10.37819/nanofab.8.305
Naveen Thakur, Nikesh Thakur, K. Kumar, V. Arya, Ashwani Kumar
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引用次数: 3

摘要

全球水污染的主要来源是纺织染料。这些工业生产的高稳定性有机染料未经处理就释放到附近的池塘、湖泊和河流中。本文采用微波辅助降解孔雀石绿(MG)染料的方法,通过包埋植物堇青石(TC),合成了掺杂镍的锐钛矿相TiO2纳米颗粒(Ni-ATD NPs)。合成的纳米颗粒在400℃的温度下煅烧以获得锐钛矿相。用不同的表征方法对合成的Ni-ATD纳米粒子进行了分析。X射线衍射(XRD)和拉曼分析证实了具有晶粒尺寸为11nm的四方结构的Ni-ATD NP的结晶性质。扫描电子显微镜(SEM)测定了合成的纳米颗粒的球形表面形态。根据紫外可见光谱,Ni-ATD NPs的吸收峰起源于360至370nm,其中带隙为3.45eV。使用Ni-ATD NP在紫外线(UV)下90分钟评估了对MG染料的光催化活性,其表现出高达100%的降解。
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Encapsulation of Tinospora cordifolia plant in Ni doped TiO2 nanoparticles for the degradation of malachite green dye
The primary global source of water pollution is textile dyes. Highly stable organic dyes are produced by these industries that are released untreated into nearby ponds, lakes and rivers. This paper is devoted to synthesis of nickle doped anatase phase of TiO2 nanoparticles (Ni-ATD NPs) by encapsulating plant Tinospora cordifolia (TC) through microwave assisted method for degradation of malachite green (MG) dye. The synthesized NPs were calcinated at 400 oC temperature to achieve the anatase phase. The synthesized Ni-ATD NPs were analysed with different characterization methods. X-ray diffraction (XRD) and Raman analysis confirmed the crystalline nature for Ni-ATD NPs with a tetragonal structure having crystallite size of 11 nm. Scanning electron microscope (SEM) determined the spherical surface morphology for synthesized NPs. The absorption peaks of Ni-ATD NPs were originated from 360 to 370 nm from UV-Visible spectroscopy in which the bandgap was found to be 3.45 eV. The photocatalytic activity for MG dye was evaluated under ultra-violet (UV) light using Ni-ATD NPs for 90 minutes which exhibited the degradation up to 100 %.
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来源期刊
Nanofabrication
Nanofabrication NANOSCIENCE & NANOTECHNOLOGY-
自引率
10.30%
发文量
13
审稿时长
16 weeks
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