一种新型三元能化合物:DAF/DNP/H2O共晶

IF 1.7 3区材料科学 Q3 CHEMISTRY, APPLIED Journal of Energetic Materials Pub Date : 2022-01-20 DOI:10.1080/07370652.2022.2028035

Xiaopeng Zhang, Yige Wu, Shaohua Jin, Guanchao Lan, Xiaojun Wang, Jun-feng Wang, Fenqing Shang, Shu-sen Chen, Junyi Du, Q. Shu

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A novel ternary energetic compound: DAF/DNP/H2O cocrystal

ABSTRACT A novel ternary energetic cocrystal composed of 3,4-diaminofurazan (DAF), 3,4-dinitropyrazole (DNP), and H2O in a 1:1:1 stoichiometry with low impact sensitivity is reported. This cocrystal has a predicted detonation velocity higher than DAF and TNT. Preliminary attempts are reported to obtain the even more energetic cocrystals DAF/DNP and DAF/DNP/H2O2. For the latter, an original approach based on the urea/H2O2 cocrystal as a source of H2O2 is described.

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来源期刊

Journal of Energetic Materials 工程技术-材料科学：综合

CiteScore

5.70

自引率

4.80%

发文量

审稿时长

1.8 months

期刊介绍： The Journal of Energetic Materials fills the need for an international forum of scientific and technical interchange in the disciplines of explosives, propellants, and pyrotechnics. It is a refereed publication which is published quarterly. Molecular orbital calculations, synthetic and analytical chemistry, formulation, ignition and detonation properties, thermal decomposition, hazards testing, biotechnology, and toxicological and environmental aspects of energetic materials production are appropriate subjects for articles submitted to the Journal.