具有氢键的超分子含硫聚合物

IF 2.1 3区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Journal of Sulfur Chemistry Pub Date : 2023-03-04 DOI:10.1080/17415993.2023.2183773

Yuichiro Kobayashi , Yuki Yamagishi , Ryuto Nishimura , Chun-Lin Xiao , Daiki Kitano , Akiyoshi Horiguchi , Shun Hashimoto , Hiroyasu Yamaguchi

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引用次数: 0

摘要

尽管含硫聚合物已经通过诸如共聚和反硫化的各种方法实现，但是关于其中超分子聚合物与含硫聚合物稠合的超分子含硫聚合物的合成的报道很少。本文通过在直链硫的两端引入2-脲基-4[1H]嘧啶酮（UPy）单元并通过氢键连接UPy，制备了一种超分子含硫聚合物。图形摘要

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Supramolecular sulfur-containing polymers with hydrogen bonding

Although sulfur-containing polymers have been realized by various methods such as copolymerization and reverse vulcanization, there are few reports on the synthesis of supramolecular sulfur-containing polymers in which a supramolecular polymer is fused with a sulfur-containing polymer. Herein, we prepare a supramolecular sulfur-containig polymer by introducing a 2-ureido-4[1H]pyrimidinone (UPy) unit at both ends of linear sulfur and connecting between the UPys via hydrogen bonding.

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来源期刊

Journal of Sulfur Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

4.10

自引率

9.10%

发文量

审稿时长

6-12 weeks

期刊介绍： The Journal of Sulfur Chemistry is an international journal for the dissemination of scientific results in the rapidly expanding realm of sulfur chemistry. The journal publishes high quality reviews, full papers and communications in the following areas: organic and inorganic chemistry, industrial chemistry, materials and polymer chemistry, biological chemistry and interdisciplinary studies directly related to sulfur science. Papers outlining theoretical, physical, mechanistic or synthetic studies pertaining to sulfur chemistry are welcome. Hence the target audience is made up of academic and industrial chemists with peripheral or focused interests in sulfur chemistry. Manuscripts that truly define the aims of the journal include, but are not limited to, those that offer: a) innovative use of sulfur reagents; b) new synthetic approaches to sulfur-containing biomolecules, materials or organic and organometallic compounds; c) theoretical and physical studies that facilitate the understanding of sulfur structure, bonding or reactivity; d) catalytic, selective, synthetically useful or noteworthy transformations of sulfur containing molecules; e) industrial applications of sulfur chemistry; f) unique sulfur atom or molecule involvement in interfacial phenomena; g) descriptions of solid phase or combinatorial methods involving sulfur containing substrates. Submissions pertaining to related atoms such as selenium and tellurium are also welcome. Articles offering routine heterocycle formation through established reactions of sulfur containing substrates are outside the scope of the journal.