皮革加工工业废料(石灰剥皮):生产生物柴油的潜在原料

S. Banik, TE Nafis, U. Roy, MS Islam
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引用次数: 0

摘要

利用含有高脂肪和蛋白质的皮革工业固体废物(皮革石灰肉)生产生物柴油得到了发展,这有利于废物管理和可再生能源的产生。采用溶剂萃取法从该废油中提取油。采用酸催化酯化,再用KOH进行酯交换法制备生物柴油。提取的游离脂肪酸含量高达11.19%的油脂,用80%甲醇、2.5% H2SO4在70℃条件下进行酸催化酯化反应60 min,酯化后的油脂再用60%甲醇、0.8% KOH在60℃条件下进行反式酯化反应120 min,生物柴油收率为95.81%。测定了所得生物柴油的闪点(145℃)、酸值(2.7 mg KOH/g)、密度(0.870 g/cc)、倾点(-12℃)和粘度(40℃和100℃时分别为5.79和1.2 cSt)等特性。这些特性非常接近商用生物柴油的标准。可再生皮革工业废弃物是生产生物柴油的潜在来源,既能保护环境,又能满足能源需求。[j]。工业,第57(3),131- 138,2022
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Leather processing industry waste (lime fleshing): A prospective substrate for production of biodiesel
Production of biodiesel using leather industry solid wastes (leather lime fleshing) containing high fats and proteins was developed, which benefitted both the ways to manage waste along with generation of renewable energy. Oil from this waste was obtained using solvent extraction process. Acid catalyzed esterification followed by transesterification using KOH was used in this biodiesel production process. Extracted oil containing high free fatty acid of 11.19 % was subjected to acid catalyzed esterification using 80% methanol, 2.5 % H2SO4 at 70 °C for 60 min. The esterified oil than trans esterified into biodiesel using 60% methanol and 0.8% KOH at 60 °C for 120 min. Biodiesel yield was 95.81%. Characteristics of produced biodiesel like flash point (145 oC), acid value (2.7 mg KOH/g), density (0.870 g/cc), pour point (-12 oC) and viscosity (5.79 and 1.2 cSt at 40 and 100 oC respectively) etc. were determined. These characteristics were very close to the commercial biodiesel standards. The renewable leather industry waste could be a potential sources of biodiesel production and would protect environment and contribute to energy demand. Bangladesh J. Sci. Ind. Res. 57(3), 131-138, 2022
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