无瓣海桑果实提取物等离子体合成纳米银及其对有机染料降解的催化活性

M. Mamun, M. Hossain, J. Naime, P. Dhar
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引用次数: 4

摘要

纳米银;绿色合成;表面等离子体;共振;催化活性;退化;摘要:与化学和物理技术相比,纳米颗粒的生物合成因其无毒和经济可行而变得更加容易。本研究以无花瓣海桑果实提取物为原料,从硝酸银(AgNO3)溶液中合成了植物介导的银纳米颗粒(AgNPs)。在不同的生理条件下,考察了反应时间对AgNPs合成的影响。利用表面等离子体共振(SPR)表征了纳米颗粒的大小和形貌。在紫外可见光谱中,以400-480 nm为中心的明显波段代表AgNPs的形成。FTIR光谱显示-OH基团可能在Ag还原成AgNPs过程中起重要作用。XRD揭示了AgNPs的面心立方几何结构。原子力显微镜图像分析发现合成的AgNPs的形状为球形。通过电子转移研究了AgNPs作为一种很有前途的催化剂在甲基橙和甲基红降解中的效率。AgNPs的这种催化活性可用于合成不同的化学中间体和有机转化。
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Plasmonic Nanosilver Synthesis Using Sonneratia apetala Fruit Extract and Their Catalytic Activity in Organic Dye Degradation
Nanosilver; Green synthesis; Surface plasmon; Resonance; Catalytic activity; Degradation; Sonneratia apetala ABSTRACT: Comparing to the chemical and physical techniques, biosynthesis of nanoparticles is being facilitated due to its nontoxic and economically feasible availability. In this present study, plant-mediated silver nanoparticles (AgNPs) were synthesized using the fruit extract of Sonneratia apetala from the silver nitrate (AgNO3) solution. Among different physiological conditions, effect of reaction time was investigated during the AgNPs synthesis. Surface Plasmon Resonance (SPR) characterization was conducted for verifying the nanoparticles size and morphology. A distinct band centered around 400-480 nm in the UV-Visible spectroscopy represented the formation of AgNPs. FTIR spectroscopy revealed that –OH group may play important role for the reduction of Ag to AgNPs. XRD revels the face-centered cubic geometry of AgNPs. AFM image analysis helped to find out the shape of the synthesized AgNPs is sphereical. The efficiency of AgNPs as a promising catalyst through electron transfer in the degradation of methyl orange and methyl red was investigated. This catalytic activity of AgNPs can be used to synthesis different chemical intermediates and organic transformations.
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来源期刊
Journal of Chemical Health Risks
Journal of Chemical Health Risks Environmental Science-Health, Toxicology and Mutagenesis
CiteScore
1.30
自引率
0.00%
发文量
0
审稿时长
3 weeks
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