氧酸盐和软氧酸盐基杂化材料:从合成到催化应用

IF 2.4 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Molecular and Engineering Materials Pub Date : 2020-12-08 DOI:10.1142/s2251237320300028
K. Das, Soumyajit Roy
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引用次数: 0

摘要

多组分混合材料很有趣。它们有潜力作为一个平台来展示其组件的属性。在这篇综述中,我们讨论了几种基于氧代金属盐(OM)的杂化物的催化应用。由于其结构的灵活性和巨大的性能,OM在催化领域是无与伦比的。因此,在这里,我们主要关注这种基于OM的杂化物的合成和催化。本综述表明,通过合理选择有机配体和含氧金属盐,可以提高裸含氧金属酸盐的催化性能,甚至可以提高其软质状态,即软含氧金属化物(SOMs)的催化性能。
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Oxometalate- and Soft-Oxometalate-Based Hybrid Materials: From Synthesis to Catalytic Applications
Multi-component hybrid materials are intriguing. They have the potential to act as a platform to manifest the properties of their components. In this review, we discuss the catalytic applications of few such hybrids that are based on oxometalates (OMs). Due to the structural flexibility and enormous properties, OMs are unrivaled in the field of catalysis. Thus, here we primarily focus on the synthesis and catalysis of such OM-based hybrids. The present overview shows that it is possible to improve the catalytic property of bare oxometalates and even that of their soft-matter state namely soft-oxometalates (SOMs) through rational choice of organic ligand and oxometalates.
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Journal of Molecular and Engineering Materials
Journal of Molecular and Engineering Materials MATERIALS SCIENCE, MULTIDISCIPLINARY-
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