聚合物熔体入口流涡旋生长的三维模拟

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2022-12-06 DOI:10.1515/ipp-2022-4277
H. Tseng
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引用次数: 3

摘要

摘要入口流中出现的角涡现象与聚合物流变学和聚合物加工有关。流体力学数值计算中著名的粘弹性本构方程在低表观剪切率下的相关性一直很有限。然而,在高级流变学中很少发现粘弹性流体的三维(3D)模拟。最近,在复杂流体的高级流变学中开发的加权剪切/拉伸粘度的GNF-X(扩展广义牛顿流体)本构方程已被纳入最先进的预测工程工具中。从而,对LDPE(低密度聚乙烯)熔体的入口流动进行了3D数值模拟。作为验证,预测的旋涡流线与相关实验观测结果吻合良好。更重要的是,模拟结果显示了涡流随表观剪切率、收缩比和入口角度的增长。特别是对于拉伸粘度,更强的拉伸硬化特性产生大的涡流尺寸。
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Three-dimensional simulation of vortex growth within entry flow of a polymer melt
Abstract The corner vortex phenomenon occurring in entry flow is relevant to both polymer rheology and polymer processing. The famous viscoelastic constitutive equations in numerical computations of fluid mechanics have always had limited relevance at low apparent shear rates. However, three-dimensional (3D) simulations of viscoelastic fluids have been rarely found in advanced rheology. Recently, the GNF-X (eXtended Generalized Newtonian Fluid) constitutive equation of the weighted shear/extensional viscosity developed in advanced rheology of complex fluids has been incorporated into state-of-the-art predictive engineering tools. Thereby, 3D numerical simulations of entry flow were performed for a LDPE (low-density polyethylene) melt. As a validation, the predicted vortex streamlines are in good agreement with related experimental observations. More importantly, the simulation results show the vortex growth with respect to apparent shear rates, contraction ratios, and inlet angles. In particular for extensional viscosity, the stronger extension hardening characteristic yields a large vortex size.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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