聚(4-乙烯基吡啶-共苯乙烯)原位改性皂石粘土对Cu(II)、Cd(II),Pb(II)和Mn(I)及Fe(III)离子的吸附性能

IF 0.4 Q4 CHEMISTRY, ANALYTICAL French-Ukrainian Journal of Chemistry Pub Date : 2019-12-24 DOI:10.17721/fujcv7i2p145-152
E. Yanovska, O. Nikolaeva, O. Kondratenko, L. Vretik
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引用次数: 2

摘要

用4-乙烯基吡啶和苯乙烯的共聚物(摩尔比3:1)通过自由基聚合对来自乌克兰塔什基夫斯克矿床的天然矿物皂石进行了原位改性。用红外光谱、质谱、扫描电镜等方法证实了有机聚合物4-乙烯基吡啶-苯乙烯在矿物表面的固定性。根据热重分析,合成的复合材料中固定化共聚物的量为8.5wt.%。与天然矿物皂石相比,复合材料对Cu(II)、Pb(II)和Fe(III)离子的记录吸附能力增加。
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Sorption properties of saponite clay, in situ modified by poly(4-vinylpyridine-co-styrene), towards Cu(II), Cd(II), Pb(II), Mn(ІІ) and Fe(III) ions
In situ modification with copolymer of 4-vinylpyridine and styrene (molar ratio 3:1) of natural mineral saponite from deposit Tashkivske(Ukraine) by radical polymerization was carried out. Anchorage of organic polymer 4-vinylpyridine-co- styrene on the mineral surface was proved by IR spectroscopy, mass spectrometry and scanning electron microscopy. The amount of immobilized copolymer in the synthesized composite material according to the thermogravimetric analysis is 8.5 wt.%. The recorded adsorption capacity of the composite with respect to Cu(II), Pb(II) and Fe(III) ions was increased in comparison with native mineral saponite.
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来源期刊
French-Ukrainian Journal of Chemistry
French-Ukrainian Journal of Chemistry CHEMISTRY, ANALYTICAL-
自引率
0.00%
发文量
13
审稿时长
4 weeks
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