{"title":"甲基乙烯基酮气相高分辨率紫外吸收光谱的振动结构","authors":"L. A. Koroleva, A. V. Koroleva","doi":"10.3103/S0027131422060037","DOIUrl":null,"url":null,"abstract":"<p>The resolved vibrational structure of a UV absorption spectrum of the molecule in the gas phase is obtained. The (0–0) bands of the isomers are found. The fundamental vibrational frequencies and (0–v) torsional vibration transitions for the <i>s</i>-trans and <i>s</i>-cis isomers of the molecule are found in the ground (<i>S</i><sub>0</sub>) and excited (<i>S</i><sub>1</sub>) electronic states. The 68 absorption bands are assigned completely.</p>","PeriodicalId":709,"journal":{"name":"Moscow University Chemistry Bulletin","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2022-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Vibrational Structure of a High-Resolution UV Absorption Spectrum of Methyl Vinyl Ketone in the Gas Phase\",\"authors\":\"L. A. Koroleva, A. V. Koroleva\",\"doi\":\"10.3103/S0027131422060037\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The resolved vibrational structure of a UV absorption spectrum of the molecule in the gas phase is obtained. The (0–0) bands of the isomers are found. The fundamental vibrational frequencies and (0–v) torsional vibration transitions for the <i>s</i>-trans and <i>s</i>-cis isomers of the molecule are found in the ground (<i>S</i><sub>0</sub>) and excited (<i>S</i><sub>1</sub>) electronic states. The 68 absorption bands are assigned completely.</p>\",\"PeriodicalId\":709,\"journal\":{\"name\":\"Moscow University Chemistry Bulletin\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2022-09-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Moscow University Chemistry Bulletin\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.3103/S0027131422060037\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Moscow University Chemistry Bulletin","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.3103/S0027131422060037","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Vibrational Structure of a High-Resolution UV Absorption Spectrum of Methyl Vinyl Ketone in the Gas Phase
The resolved vibrational structure of a UV absorption spectrum of the molecule in the gas phase is obtained. The (0–0) bands of the isomers are found. The fundamental vibrational frequencies and (0–v) torsional vibration transitions for the s-trans and s-cis isomers of the molecule are found in the ground (S0) and excited (S1) electronic states. The 68 absorption bands are assigned completely.
期刊介绍：
Moscow University Chemistry Bulletin is a journal that publishes review articles, original research articles, and short communications on various areas of basic and applied research in chemistry, including medical chemistry and pharmacology.
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