{"title":"（2,2′-联吡啶）（N-（1-萘基）甲基-1,3-丙二胺）氯化铂（II）的晶体结构","authors":"T. Kiwada, Aika Hirasaki, A. Odani","doi":"10.2116/XRAYSTRUCT.35.35","DOIUrl":null,"url":null,"abstract":"The crystal structure of (2,2 ′ -bipyridine)( N -(1-naphthyl)methyl-1,3-propanediamine)platinum(II) chloride was determined by X-ray crystallography. The title complex crystallized in the monoclinic space group C 2/ c and Z = 8 with cell parameters a = 23.3026(14)Å, b = 17.4118(12)Å, c = 12.3816(7)Å, β = 109.032(8) ° , V = 4749.1(6)Å 3 . The R 1 [ I > 2 σ ( I )] and wR 2 (all data) values are 0.0242 and 0.0490, respectively, for all 5435 independent reflections. In the crystal structure, disorder was observed for the N -(1-naphthyl)methyl-1,3-propanediamine moiety. Hydrogen-bond network was formed between the (2,2 ′ -bipyridine)( N -(1-naphthyl)methyl-1,3-propanediamine)platinum(II) cations and chloride anions.","PeriodicalId":23922,"journal":{"name":"X-ray Structure Analysis Online","volume":null,"pages":null},"PeriodicalIF":0.1000,"publicationDate":"2019-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Crystal Structure of (2,2′-Bipyridine)(N-(1-naphthyl)methyl-1,3-propanediamine)platinum(II) Chloride\",\"authors\":\"T. Kiwada, Aika Hirasaki, A. Odani\",\"doi\":\"10.2116/XRAYSTRUCT.35.35\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The crystal structure of (2,2 ′ -bipyridine)( N -(1-naphthyl)methyl-1,3-propanediamine)platinum(II) chloride was determined by X-ray crystallography. The title complex crystallized in the monoclinic space group C 2/ c and Z = 8 with cell parameters a = 23.3026(14)Å, b = 17.4118(12)Å, c = 12.3816(7)Å, β = 109.032(8) ° , V = 4749.1(6)Å 3 . The R 1 [ I > 2 σ ( I )] and wR 2 (all data) values are 0.0242 and 0.0490, respectively, for all 5435 independent reflections. In the crystal structure, disorder was observed for the N -(1-naphthyl)methyl-1,3-propanediamine moiety. Hydrogen-bond network was formed between the (2,2 ′ -bipyridine)( N -(1-naphthyl)methyl-1,3-propanediamine)platinum(II) cations and chloride anions.\",\"PeriodicalId\":23922,\"journal\":{\"name\":\"X-ray Structure Analysis Online\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.1000,\"publicationDate\":\"2019-06-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"X-ray Structure Analysis Online\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2116/XRAYSTRUCT.35.35\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CRYSTALLOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/XRAYSTRUCT.35.35","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
Crystal Structure of (2,2′-Bipyridine)(N-(1-naphthyl)methyl-1,3-propanediamine)platinum(II) Chloride
The crystal structure of (2,2 ′ -bipyridine)( N -(1-naphthyl)methyl-1,3-propanediamine)platinum(II) chloride was determined by X-ray crystallography. The title complex crystallized in the monoclinic space group C 2/ c and Z = 8 with cell parameters a = 23.3026(14)Å, b = 17.4118(12)Å, c = 12.3816(7)Å, β = 109.032(8) ° , V = 4749.1(6)Å 3 . The R 1 [ I > 2 σ ( I )] and wR 2 (all data) values are 0.0242 and 0.0490, respectively, for all 5435 independent reflections. In the crystal structure, disorder was observed for the N -(1-naphthyl)methyl-1,3-propanediamine moiety. Hydrogen-bond network was formed between the (2,2 ′ -bipyridine)( N -(1-naphthyl)methyl-1,3-propanediamine)platinum(II) cations and chloride anions.
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